Pressure‐Tuning Photochemistry of Metal Complexes in Solution

Eldik, Rudi van; Ford, Peter C.

doi:10.1002/9780470133552.ch2

Cited by 13 publications

(1 citation statement)

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“…Early literature may be consulted to access both technical information and types of reactions studied; the latter include inorganic, bioinorganic, and organometallic reactions. 102,[124][125][126][127][128][129][130][131][132][133][134] The means by which high pressure is delivered to the reaction system is no different from that employed for thermal-based reactions.…”

Section: Rapid Reactionsmentioning

confidence: 99%

Application of High Pressure in the Elucidation of Inorganic and Bioinorganic Reaction Mechanisms

Hubbard¹,

Eldik²

2010

Physical Inorganic Chemistry

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Section: Rapid Reactionsmentioning

confidence: 99%

Application of High Pressure in the Elucidation of Inorganic and Bioinorganic Reaction Mechanisms

Hubbard¹,

Eldik²

2010

Physical Inorganic Chemistry

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High Pressure Chemistry

Hubbard

Eldik

2005

Kirk-Othmer Encyclopedia of Chemical Technology

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The technology associated with application of hydrostatic pressure in chemistry is presented. Apparatus and equipment range from a straightforward autoclave‐type arrangement to more sophisticated techniques of subjecting materials or chemical reactions in solution to pressure, and monitoring events caused by pressure application while the system is under pressure (ie, in situ ). Spectroscopic detection is the principal monitoring technique in in situ methods. The wide span of time ranges of changes taking place during a pressure cycle requires different types of technologies and these are described. The type of system under investigation directs the choice of method and the range of pressure applied. For synthetic and preparative solution chemistry, pressures up to a few thousand megapascals (MPa) have been used. For processing of materials to bring about a change in properties, pressures up to 600 MPa are usually adequate, whereas for most mechanistic studies pressures > 200 MPa are rarely used (1 atm = 1.01325 × 10 5 Pa; 1 Pa = 1 N/m 2 ). Examples of systems studied from organic chemistry, inorganic chemistry, bioinorganic chemistry, and colloid chemistry are provided. These clearly illustrate the value of applying hydrostatic pressure and demonstrate insight into understanding physicochemical and chemical changes that occur. Such insight is not normally achievable by other experimental approaches and highlights the unique value and success of high pressure technology in chemistry.

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Teil II: Elektronentransfer / Photo-und strahlungsinduzierte Reaktionen

Eldik

Hubbard²

2000

Chemie in unserer Zeit

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Aufklärung anorganischer Reaktionsmechanismen307 2 Abb. 2. ∆V 0 cell gegen z ox 2 -z red 2 für einige ausgewählte Fe(II)/Fe(III)-Komplexe. 3 Abb. 3. Volumenprofil für den reversiblen Elektronentransfer [Ru III (NH 3 ) 5 L] 3+ + cyt c II ↔ [Ru II (NH 3 ) 5 L] 2+ + cyt c II I ; L = Isonicotinamid. Reaktanten Übergangszustand Produkte Reaktionskoordinate Relatives partielles molares Volumen, cm 3 mol -1 9 Abb. 9. Energie-und Volumenprofile für die reversible Bindung von CO an einen lacunaren Fe(II)-Komplex. Relatives partielles, molares Volumen, cm 3 mol -1 15 Reaktanten Übergangszustand Produkte Reaktionskoordinate Relatives partielles, molares Volumen, cm 3 mol -1 Abb. 14. Volumenprofil für die Reaktion von Methylradikalen mit dem Nitrilotriacetat-Komplex des Co(II); R = CH 3 . Abb. 15. Volumenprofil für die Reaktion eines aliphatischen Radikals mit [Cr(H 2 O) 6 ] 2+ ; R = C(CH 3 ) 2 OH.

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Pressure‐Tuning Photochemistry of Metal Complexes in Solution

Cited by 13 publications

References 145 publications

Application of High Pressure in the Elucidation of Inorganic and Bioinorganic Reaction Mechanisms

Application of High Pressure in the Elucidation of Inorganic and Bioinorganic Reaction Mechanisms

High Pressure Chemistry

Teil II: Elektronentransfer / Photo-und strahlungsinduzierte Reaktionen

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