Pressure profile separation of phenolic liquid compounds from cashew (Anacardium occidentale) shell with supercritical carbon dioxide and aspects of its phase equilibria

Setianto, Wahyu; Yoshikawa, Suguru; Smith, Richard L.; Inomata, Hiroshi; Florusse, Louw J.; Peters, Cor J.

doi:10.1016/j.supflu.2008.11.018

Cited by 41 publications

(30 citation statements)

References 17 publications

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“…The samples presented distinct behaviors, even the two natural CNSLs. The identification of the peaks was based on the work by Setianto et al [15] , Kumar et al [16] , and Philip et al [18] . The various peaks refer to the respective trienes, dienes and monoenes, whose retention time increased in the mentioned order.…”

Section: Differential Scanning Calorimetry (Dsc)mentioning

confidence: 99%

“…The lowest value registered by the CNSLNS should be related to the lowest medium molar mass since it contains more cardanol (MM medium 301.5 g.mol -1 ). Cardol and anacardic acid have a medium molar mass of 315.4 and 342.9 g.mol -1 [15] . The cardanol presents E value of 45.4 kJ.mol -1 [28] , in agreement with the proposed explanation.…”

Section: High Performance Liquid Chromatography (Hplc)mentioning

confidence: 99%

“…In the natural CNSL they are: anacardic acid (46-65%); cardol (15-31%); cardanol (10-22%) and traces of methyl-cardol ( Figure 1) [15,16] . The anacardic acids are thermically unstable and are easily decarboxylated during the hot extraction process.…”

Section: Introductionmentioning

confidence: 99%

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Comparison between physico-chemical properties of the technical Cashew Nut Shell Liquid (CNSL) and those natural extracted from solvent and pressing

et al. 2011

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Cashew nut shell liquid (CNSL) is a by-product of the cashew kernel industry, applied mainly to produce polymeric derivatives. The technical CNSL (CNSLT) was obtained industrially, extracted by roasting the cashew nut shells at temperatures between 180 and 200 °C. Two methods were used to produce natural CNSL. For the extraction of CNSLNP, the cashew nut shells were pressed at room temperature. CNSLNS was extracted in hexane at room temperature and recovered at 50 °C. A comparison was made of the composition determined by HPLC and properties generated by viscosity measurements and also by TG, DSC and IPDT (integral procedural decomposition temperature). Natural CNSLs displayed higher content of cardol and anacardic acid and lower percentage of cardanol than CNSLT. The higher content of cardanol in CNSLNS was the major difference between natural CNSLs. CNSLNP had higher levels of impurity, higher viscosity, lower thermoxidative stabilities and lower ebullition temperature. The CNSL obtained by cold solvent extraction and recovery at 50 °C better preserves the original properties of the liquid.

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Section: Differential Scanning Calorimetry (Dsc)mentioning

confidence: 99%

Section: High Performance Liquid Chromatography (Hplc)mentioning

confidence: 99%

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Comparison between physico-chemical properties of the technical Cashew Nut Shell Liquid (CNSL) and those natural extracted from solvent and pressing

et al. 2011

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“…Vatanara et al (2005) also reported that beclomethasone diproprionate and budesonide showed the zones at 24.3 MPa. Furthermore, Setianto et al (2009) calculated phase behavior of of CNSL and CO 2 system using Peng-Robinson EOS. It was reported that the cross-over zone appeared at pressures between 12 to 20 Mpa.…”

Section: Results and Discussion Experimental Solubilitymentioning

confidence: 99%

“…Supercritical CO 2 has been explored to be utilized as solvent for extraction of many natural product (Reverchon, 1997;Reverchon and Marrone, 2001;Westerman et al, 2006;Zaidul et al, 2007;Machmudah et al, 2008;Norulaini et al, 2009;Setianto et al, 2009;Vargas et al, 2010;Setianto, 2011;Fornari et al, 2012;Mesomo et al, 2012;Mesomo et al, 2013). Using SC-CO 2 solvent allows extraction processes to operate near ambient temperature.…”

Section: Introductionmentioning

confidence: 99%

Palm Kernel Oil Solubity Examination and Its Modeling in Extraction Process Using Supercritical Carbon Dioxide

Setianto

Atmaji

Anggoro

2013

Reaktor

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The nutritional and bio‐active constituents, functional activities, and industrial applications of cashew (Anacardium occidentale): A review

Chen,

Li,

Guo

et al. 2023

Food Frontiers

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Cashew nut is a globally popular nut not only for its delicious and crunchy flavor but also for bioactive compounds, which present positive benefits to human health. Different parts of cashew have characteristic compounds. The kernel of cashew nut is rich in fatty acids, the testa is rich in polyphenols, cashew apple is rich in polyphenols and carotenoids, and phenols with aliphatic long chain are present in the cashew nutshell liquid. Therefore, the edible part of cashew possesses a wide range of bioactive compounds, with reported biological properties, including anti‐tumor, brain health, cardiovascular and cerebrovascular protection, anti‐diabetic, gastroprotection, pathophysiological disorders protection, and antioxidant. On the other hand, the inedible part of cashew, the cashew nutshell liquid, could play an important role in the industry as surface coatings, insulating formulations and so on. Hence, there are considerable demands to increase the added value of cashew, thereby exploring greater economic value. Thus, this review summarizes nutrients, bioactive compounds, biological functions, and applications of Anacardium occidentale to provide a theoretical basis and inspiration for further in‐depth studies and utilization.

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Pressure profile separation of phenolic liquid compounds from cashew (Anacardium occidentale) shell with supercritical carbon dioxide and aspects of its phase equilibria

Cited by 41 publications

References 17 publications

Comparison between physico-chemical properties of the technical Cashew Nut Shell Liquid (CNSL) and those natural extracted from solvent and pressing

Comparison between physico-chemical properties of the technical Cashew Nut Shell Liquid (CNSL) and those natural extracted from solvent and pressing

Palm Kernel Oil Solubity Examination and Its Modeling in Extraction Process Using Supercritical Carbon Dioxide

The nutritional and bio‐active constituents, functional activities, and industrial applications of cashew (Anacardium occidentale): A review

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