2013
DOI: 10.1103/physreve.87.012405
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Pressure-induced evaporation dynamics of gold nanoparticles on oxide substrate

Abstract: Here we report thermal evaporation dynamics of Au nanoparticles on single crystal oxide substrates, including MgO, SrTiO(3), and Al(2)O(3). The size reduction rate of Au nanoparticles via thermal treatments is strongly dependent on not only temperature but also pressure. Lowering the pressure of inert Ar gas from 10(5) to 10 Pa increases the size reduction rate over 30 times in the temperature range 800 °C-950 °C. The temperature dependence is solely due to the variation of saturated vapor pressure of Au, wher… Show more

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Cited by 18 publications
(17 citation statements)
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“…We fabricated the microchannel on a fused silica substrate by conventional photolithography and utilized Au catalyst for VLS growth of SnO 2 nanowires (typical diameter of 10–20 nm)333435. It should be noted that we intentionally did not use electron beam lithography as we wanted to target future commercial use.…”
Section: Resultsmentioning
confidence: 99%
“…We fabricated the microchannel on a fused silica substrate by conventional photolithography and utilized Au catalyst for VLS growth of SnO 2 nanowires (typical diameter of 10–20 nm)333435. It should be noted that we intentionally did not use electron beam lithography as we wanted to target future commercial use.…”
Section: Resultsmentioning
confidence: 99%
“…Along with the decreased density, the size of NPs also decreased accordingly with the increased dwelling time. The reduction of size may be caused by the evaporation of Au at high temperature of annealing such that when the dwelling time increases, the rate of evaporation can also increase accordingly with the increased dwelling time [ 43 ]. Consequently, when the sample was annealed at 950 °C for 150 s, the AH and LD of the Au NPs were 30.2 and 123.5 nm, respectively, as shown in Fig.…”
Section: Resultsmentioning
confidence: 99%
“…6 (c),(c- 1 ). The size reduction at a higher surface temperature associated with the density decrease is against the general trend of surface diffusion, and this can be possibly due to the enhanced evaporation of nanoscale Au as a function of AT, which can similarly witnessed on Si 43 , MgO, SrTiO 3 , and Al 2 O 3 44 . To specify the size and density evolution, the average height (AH), lateral diameter (LD) and average density (AD) are summarized in Fig.…”
Section: Resultsmentioning
confidence: 91%