1985
DOI: 10.1007/bf02744059
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Pressure dependence of electrical resistivities of some charge transfer complexes

Abstract: The electrical resistivities of organic charge transfer complexes namely dithionaphthalene-iodine (1:1), anthracene-trinitrobenzene (1 : 1), pyrene-212 and benzidine-rCNQ (dichloromethane) have been studied upto 2-8 GPa pressure. An increase in the electrical resistivities shows that the conduction is due to a hopping mechanism involving localized levels near the band edges or is trap-limited. Pressure can increase both the density of defects and intermolecular orbital overlap as opposite effects.

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“…The electrical conductivity of TCNQ and anthracene charge transfer complexes with pyrene and benzedene was measured [11,12]. It was proposed that the conduction is due to hopping mechanism.…”
Section: Introductionmentioning
confidence: 99%
“…The electrical conductivity of TCNQ and anthracene charge transfer complexes with pyrene and benzedene was measured [11,12]. It was proposed that the conduction is due to hopping mechanism.…”
Section: Introductionmentioning
confidence: 99%