“…In this process, not only organic components play an important role, but also inorganic components have a crucial influence on the formation of organic matter and generation of oil and gas, e.g., water, clay minerals and transitional metal elements can be used as reactants or catalysts (Liu et al, 2019). Previous studies have shown that major shale formations are generally associated with volcanic ash layers (Liu et al, 2021), such as the Upper Devonian-Lower Carboniferous Bakken Formation in the Williston Basin (Dennison and Textoris, 1970), the Middle Devonian Marcellus Formation in the Appalachian Basin (Hayward, 2012), the Upper Cretaceous Eagle Ford Formation in Gulf Coast Basin (Robison, 1997;Duggen et al, 2007;Lee et al, 2018), the Devonian-Carboniferous Bazhenov Formation in Western Siberia, Russia (Shaldybin et al, 2019;Liang et al, 2020), the Jurassic Vaca Muerta Formation in Neuquen Basin, Argentina (Kietzmann et al, 2014), etc. In the Mesozoic and Cenozoic terrigenous petroliferous basins in China, organic-rich shale is also generally accompanied by volcanic activity (Zhao and Liu, 2016), such as the Qingshankou Formation (Gao et al, 2008;Lee et al, 2018) and Yingcheng Formation (Shan et al, 2013) in the Songliao Basin, Shahejie Formation in the Bohai Bay Basin (Du et al, 2014), Yanchang Formation in the Ordos Basin (Qiu et al, 2009;Zhang et al, 2009), Hargau (Li et al, 2010) and Lucaogou (Wu et al, 2012) formations in the Santanghu Basin, and Longmaxi Formation in the Sichuan Basin (Zhao et al, 2015).…”