Preparative Methods

Grannec, J.; Lozano, L.

doi:10.1016/b978-0-12-313370-0.50007-4

Cited by 19 publications

(7 citation statements)

References 269 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…The direct F 2 -gas fluorination process was performed in a dedicated fluorine equipment using special handling procedures. 41 A cylindrical nickel reactor of approx. 50 cm in length and offering a volume of approx.…”

Section: Fluorination Experimentsmentioning

confidence: 99%

One-shot versus stepwise gas–solid synthesis of iron trifluoride: investigation of pure molecular F2 fluorination of chloride precursors

et al. 2013

View full text Add to dashboard Cite

Section: Fluorination Experimentsmentioning

confidence: 99%

One-shot versus stepwise gas–solid synthesis of iron trifluoride: investigation of pure molecular F2 fluorination of chloride precursors

et al. 2013

View full text Add to dashboard Cite

“…The list of the available techniques for the elaboration of fluorides is quite long, and several articles have been devoted to the development of the synthesis procedures during successive periods. A comprehensive review on solid–solid, gas–solid, solution–solid reactions, eventually under low or high pressure, was published in 1985 by Grannec and Lozano . Two decades later, mild reaction conditions (related to “chimie douce”, despite the agressive nature of numerous involved fluorides) were prevailing, according to Lutar, Borrmann, and Leblanc .…”

Section: Introductionmentioning

confidence: 99%

Crystal Chemistry and Selected Physical Properties of Inorganic Fluorides and Oxide-Fluorides

2014

View full text Add to dashboard Cite

The stereochemistry of fluorides will be discussed in terms of dimensionality. This dimensionality, from 0D to 3D, is related to the connectivity of the building MX n m− units containing the metal M (M = aluminum, transition metal, or rare earth elements, X = F, O, N, S). These building units share eventually one, two, or three fluorine or oxygen atoms (corner, edge, or face of the MX n m− polyhedra) to form limited polyanions, infinite chains or layers, or a 3D network. Consequently, the structures will be presented according to their dimensionality, to their structural family, and to the nature of the building units. Imaginative associations of the building units will be eventually used to homogenize the structural descriptions. At the end of each section, some outstanding physical properties will be briefly presented and related to the structural data: ionic conductivity, superconductivity, ferroelasticity, and magnetism.The reader should be aware that the IUPAC nomenclature suggests "fluorido" instead of "fluoro" that is used all along this Review. All crystal structure projections were realized with Diamond software (Diamond -Crystal and Molecular Structure

show abstract

“…The description of the metal #uoride handling and disposal lines can also be found in previous articles (9). Since the "nal compounds are sensitive to moisture, their preparation and their handling requires strict exclusion of moisture.…”

Section: Preparative Methodsmentioning

confidence: 99%

Preparation, Magnetic Properties, and Pressure-Induced Transitions of Some MIIMIVF6 (MII=Ni, Pd, Cu; MIV=Pd, Pt, Sn) Complex Fluorides

Tressaud

Bartlett

2001

Journal of Solid State Chemistry

View full text Add to dashboard Cite

Preparative Methods

Cited by 19 publications

References 269 publications

One-shot versus stepwise gas–solid synthesis of iron trifluoride: investigation of pure molecular F2 fluorination of chloride precursors

One-shot versus stepwise gas–solid synthesis of iron trifluoride: investigation of pure molecular F2 fluorination of chloride precursors

Crystal Chemistry and Selected Physical Properties of Inorganic Fluorides and Oxide-Fluorides

Preparation, Magnetic Properties, and Pressure-Induced Transitions of Some MIIMIVF6 (MII=Ni, Pd, Cu; MIV=Pd, Pt, Sn) Complex Fluorides

Contact Info

Product

Resources

About