Preparative and Catalytic Properties of MoVI Mononuclear and Metallosupramolecular Coordination Assemblies Bearing Hydrazonato Ligands
Mirna Mandarić,
Edi Topić,
Dominique Agustin
et al.
Abstract:A series of polynuclear, dinuclear, and mononuclear Mo(VI) complexes were synthesized with the hydrazonato ligands derived from 5-methoxysalicylaldehyde and the corresponding hydrazides (isonicotinic hydrazide (H2L1), nicotinic hydrazide (H2L2), 2-aminobenzhydrazide (H2L3), or 4-aminobenzhydrazide (H2L4)). The metallosupramolecular compounds obtained from non-coordinating solvents, [MoO2(L1,2)]n (1 and 2) and [MoO2(L3,4)]2 (3 and 4), formed infinite structures and metallacycles, respectively. By blocking two c… Show more
POM-based hybrids have been synthesized and used as (pre)catalyst. Quantum chemical calculations have been applied to evaluate the hybridtype stability.
POM-based hybrids have been synthesized and used as (pre)catalyst. Quantum chemical calculations have been applied to evaluate the hybridtype stability.
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