Preparation of μ-(η5:η5-Fulvalene)-di-μ-hydrido-bis(η5-cyclopentadienyltitanium) by the reduction of Cp2TiCl2 with LiAlH4 in aromatic solvents

Thermolysis of titanocene methyl compounds bearing t-butyl- and benzyltetramethylcyclopentadienyl ligands

“…Accordingly, the pairs of cyclopentadienyl methyl groups residing at hinge position of the bent titanocene C(8)/C(9) and C(19)/C (20) and the methyl groups C(6) and C (22) being close to the methyl C(27) were deviated from the least-squares planes of the cyclopentadienyl rings by only 0.221-0.294(2) Å away from titanium. Such values indicate a very low steric hindrance for bent permethyltitanocene compounds.…”

One-pot synthesis of 5-ethylidene-2-norbornene from 1,3-butadiene and cyclopentadiene in the presence of Cp2TiCl2-LiAlH4.

“…The Al:Ti ratio =4 appeares to be optimum for the production of Fu2Cp2Ti2H2, although the Al:Ti ratio=2 is sufficient for its production. 20) In our experiments, the fact that no ENB was formed in a reaction employing 2 equiv. or less of LiAlH4 to Cp2TiCl2 (Table 2) may be correlated to insufficient formation of the above Ti species.…”

Synthesis and structure of dinuclear dimethylene- or 1,4-phenylene-linked bis(decamethyltitanoceneoxide) (TiIII) complexes

“…Unfortunately, the glycol moiety is strongly disordered in two equally populated positions (denoted A, B) subtending the angle O(1A)eTi(1)eO(1B) of 17.08 (18) that is perpendicular to the Cg(1), Ti(1), and (Cg(2) plane (see Fig. 3a).…”