“…Nowadays, most commercial red phosphors are based on Eu 3+ doped sulfides and oxysulfides such as Y 2 O 2 S:Eu 3+ and SrY 2 S 4 :Eu 3+ [7,8]. However, some drawbacks of these phosphors are low luminous efficiency, short lifetimes and poor chemical stability, which limit their practical applications.…”
“…Nowadays, most commercial red phosphors are based on Eu 3+ doped sulfides and oxysulfides such as Y 2 O 2 S:Eu 3+ and SrY 2 S 4 :Eu 3+ [7,8]. However, some drawbacks of these phosphors are low luminous efficiency, short lifetimes and poor chemical stability, which limit their practical applications.…”
“…In order to solve such problem, another approach is proposed by combining the red/green/blue tri-color phosphors with the near-ultraviolet (n-UV) chip peaking at 370-410 nm or conjunction with green and red phosphors by using blue chip, which can offer higher CRI and excellent color uniformity [1,7]. However, the current commercial red phosphors are mainly sulfides and nitrides such as Y 2 O 2 S:Eu 3 þ [8], CaAlSiN 3 :Eu 2 þ [9], and Ba 2 Si 5 N 8 : Eu 2 þ [10], which still limited their applications extensively due to the chemical instability and rigorous synthetic routes. Therefore, it is highly urgent and desirable to develop novel and stable red phosphors.…”
“…[1][2][3][4][5][6][7][8][9][10] In particular, white LEDs fabricated from phosphors are gaining significant attention because they have many advantages over the existing incandescent lamps. [6][7][8][9][10][11][12] Even though a blue light GaN (gallium nitride) LED chip loaded with a yellow phosphor is now widely used as a conventional white LED, this combination have serious drawbacks in the color rendering index. Because of this, the white LEDs based on red, green, and blue primary colors have been explored.…”
Section: Introductionmentioning
confidence: 99%
“…[3][4][5][6][7][8][9][10][11] Since the photoluminescence (PL) intensity of the red phosphor is lower than that of the green and blue phosphors, the use of a phosphor mixture containing a large amount of red phosphors is required for sufficient color rendering. [8][9][10] The alkaline earth sulfides are widely used as the red emitting phosphors. Among the red phosphors, CaS:Eu 2+ is considered as the most promising red emitting phosphor because of its a deep red emission with nice color purity.…”
Section: Introductionmentioning
confidence: 99%
“…Among the red phosphors, CaS:Eu 2+ is considered as the most promising red emitting phosphor because of its a deep red emission with nice color purity. [9][10][11][12][13] However, the application of CaS:Eu 2+ has been limited by their instability when exposed to moisture. The problems with red phosphors should be solved for the advancement of white LEDs.…”
To improve the moisture stability of the CaS:Eu 2 + red phosphor, surface coatings with silica nanoparticles were performed using five different methods, i.e., P 1 , P 2 , P 3 , P 4 , and P 5 . The phosphors were coated with silica nanoparticles using a dip coating method (P 1 ) and sol-gel method (P 2 ). The phosphors were coated using a solution containing silica nanoparticles and poly(1-vinyl-2-pyrrolidone), PVP, (P 3 ). The phosphors were also coated with silica nanoparticles by reacting with the 1-vinyl-2-pyrrolidone (VP) monomer (P 4 ) or by reacting with mixtures containing VP and tetraethylorthosilicate (P 5 ). A decrease in the photoluminescence (PL) intensity was observed regardless of the coating methods. However, the moisture stability of the phosphors was enhanced by the coating when aged in a temperature-controlled humidity chamber. Among these methods, the P 4 (or P 5 ) method exhibited the greatest increase in moisture stability of the phosphors. The coated phosphors showed a relatively constant intensity with aging time, whereas the uncoated phosphor showed a decrease.
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