Preparation of transparent Bi₂O₃‐ZnO‐B₂O₃ glass by conventional sintering at low temperatures

Abstract

Glass components fabricated by the sintering route have wide‐ranging applications. However, one issue is that the crystallization tendency of glass powders often leads to residual pore‐glass interfaces and crystal‐glass interfaces, thereby causing strong light scattering and rendering the sintered glass opaque. This issue is particularly pronounced in glasses with a low glass transition temperature (Tg) due to their weak bonding and thus high crystallization tendency. In the present study, a Bi2O3‐ZnO‐B2O3 glass with a low Tg of 364°C was fabricated using the conventional sintering method to explore whether transparent glass materials can be obtained. The temperature range of crystallization of the glass powders was analyzed using differential scanning calorimetry. X‐ray diffraction was employed to analyze the crystalline phases formed in the sintered glasses. The microstructure of the sintered glasses was examined using scanning electron microscopy. The optical transmittance of the sintered glasses was measured using ultraviolet‐visible spectroscopy. The results show that transparent sintered glasses with the highest transmittance of 54% at the wavelength of 650 nm can be obtained by using a coarser initial particle size, lower forming pressure, and an appropriate sintering temperature/time (430°C/30 min). It is suggested that this combination of processing parameters can suppress glass crystallization while maintaining a low glass viscosity during sintering.