Preparation of TiO2/boron-doped diamond/Ta multilayer films and use as electrode materials for supercapacitors

Shi, Chao; Li, Hongji; Li, Cuiping; Li, Mingji; Qu, Changqing; Yang, Baohe

doi:10.1016/j.apsusc.2015.10.006

Cited by 31 publications

(5 citation statements)

References 41 publications

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“…To the best of our knowledge, scarce works have been reported dealing with the functionalization of diamond using pseudo-capacitive materials for supercapacitor applications, which provided an improvement of capacitive properties owing to their faradaic reactions involved during the charge-discharge process. [35][36][37] In this study, we have elaborated a novel 3-D hierarchical hetero-nanostructure composed of an electroactive conducting polymer (PEDOT), boron-doped crystalline diamond and SiNWs (hereafter denoted as PEDOT-D@SiNWs) to be employed as electrodes in a symmetric micro-supercapacitor device. The hybrid electrode was characterized by scanning electron microscopy (SEM), high resolution scanningtransmission electron microscopy (HRSTEM) equipped with EDX analysis and X-ray photoelectron spectroscopy (XPS) techniques.…”

Section: Introductionmentioning

confidence: 99%

“…These values were clearly enhanced compared to those of our previous MSCs based on chemical vapor deposition (CVD)-grown SiNWs (AC = 0.023–0.050 mF cm –2 ) − or SiNTrs (AC = 0.058 mF cm –2 ), reflecting the enormous potential of the diamond coating for SiNW-based MSC devices. To the best of our knowledge, scarce works have been reported dealing with the functionalization of diamond using pseudocapacitive materials for supercapacitor applications, which provided an improvement of capacitive properties owing to the faradic reactions involved during the charge–discharge process. − …”

Section: Introductionmentioning

confidence: 99%

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Designing 3D Multihierarchical Heteronanostructures for High-Performance On-Chip Hybrid Supercapacitors: Poly(3,4-(ethylenedioxy)thiophene)-Coated Diamond/Silicon Nanowire Electrodes in an Aprotic Ionic Liquid

Aradilla

Gao

Lewes-Malandrakis

et al. 2016

ACS Appl. Mater. Interfaces

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A versatile and robust hierarchically multifunctionalized nanostructured material made of poly(3,4-(ethylenedioxy)thiophene) (PEDOT)-coated diamond@silicon nanowires has been demonstrated to be an excellent capacitive electrode for supercapacitor devices. Thus, the electrochemical deposition of nanometric PEDOT films on diamond-coated silicon nanowire (SiNW) electrodes using N-methyl-N-propylpyrrolidinium bis((trifluoromethyl)sulfonyl)imide ionic liquid displayed a specific capacitance value of 140 F g(-1) at a scan rate of 1 mV s(-1). The as-grown functionalized electrodes were evaluated in a symmetric planar microsupercapacitor using butyltrimethylammonium bis((trifluoromethyl)sulfonyl)imide aprotic ionic liquid as the electrolyte. The device exhibited extraordinary energy and power density values of 26 mJ cm(-2) and 1.3 mW cm(-2) within a large voltage cell of 2.5 V, respectively. In addition, the system was able to retain 80% of its initial capacitance after 15 000 galvanostatic charge-discharge cycles at a high current density of 1 mA cm(-2) while maintaining a Coulombic efficiency around 100%. Therefore, this multifunctionalized hybrid device represents one of the best electrochemical performances concerning coated SiNW electrodes for a high-energy advanced on-chip supercapacitor.

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Section: Introductionmentioning

confidence: 99%

Section: Introductionmentioning

confidence: 99%

Designing 3D Multihierarchical Heteronanostructures for High-Performance On-Chip Hybrid Supercapacitors: Poly(3,4-(ethylenedioxy)thiophene)-Coated Diamond/Silicon Nanowire Electrodes in an Aprotic Ionic Liquid

Aradilla

Gao

Lewes-Malandrakis

et al. 2016

ACS Appl. Mater. Interfaces

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“…The major advantage of these composite materials is that the PC stability can be improved through using a rigid coating or scaffolding material ( Kovalenko et al, 2010 ; Liu and Li, 2020 ), while also providing other synergistic effects such as improved P density ( Aradilla et al, 2016 ). The materials used to create diamond-based composites include polymers such as polyaniline (PANI) ( Kovalenko et al, 2010 ; da Silva et al, 2018 ), polypyrrole (PPy) ( Hébert et al, 2015 ), and poly [3, 4-(ethylenedioxy) thiophene] (PEDOT) ( Aradilla et al, 2016 ); transition metals such as nickel ( Shi et al, 2016 ); and transition metal oxides such as manganese oxide ( Yu et al, 2015 ), nickel hydroxide ( Gao and Nebel, 2015 ), ruthenium oxide ( Spătaru et al, 2007 ), and titanium oxide ( Shi et al, 2015 ). The fabrication methods for these composite materials generally involve either subsequent growth/deposition steps or adding diamond nanoparticles to a polymer synthesis process.…”

Section: Current Experimental Progress Of Diamond Supercapacitorsmentioning

confidence: 99%

Diamond Supercapacitors: Towards Durable, Safe, and Biocompatible Aqueous-Based Energy Storage

et al. 2022

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Durable and safe energy storage is required for the next generation of miniature bioelectronic devices, in which aqueous electrolytes are preferred due to the advantages in safety, low cost, and high conductivity. While rechargeable aqueous batteries are among the primary choices with relatively low power requirements, their lifetime is generally limited to a few thousand charging/discharging cycles as the electrode material can degrade due to electrochemical reactions. Electrical double layer capacitors (EDLCs) possess increased cycling stability and power density, although with as-yet lower energy density, due to quick electrical adsorption and desorption of ions without involving chemical reactions. However, in aqueous solution, chemical reactions which cause electrode degradation and produce hazardous species can occur when the voltage is increased beyond its operation window to improve the energy density. Diamond is a durable and biocompatible electrode material for supercapacitors, while at the same time provides a larger voltage window in biological environments. For applications requiring higher energy density, diamond-based pseudocapacitors (PCs) have also been developed, which combine EDLCs with fast electrochemical reactions. Here we inspect the properties of diamond-related materials and discuss their advantages and disadvantages when used as EDLC and PC materials. We argue that further optimization of the diamond surface chemistry and morphology, guided by computational modelling of the interface, can lead to supercapacitors with enhanced performance. We envisage that such diamond-based supercapacitors could be used in a wide range of applications and in particular those requiring high performance in biomedical applications.

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“…Shi et al . reported the BDD films grown on a Ta plate as a substrate for Ti layer (100 nm) deposition by magnetron sputtering, followed by anodization in fluoride‐containing solution.…”

Section: Diamond‐based Compositesmentioning

confidence: 99%

“…Titania nanotubes (TiO 2 NT) modified by boron‐doped diamond is a promising candidate for the fabrication of supercapacitors . On the contrary to Shi et al., the highly ordered layer of titania (8 μm in length and 30 nm in internal diameter) was produced by anodization of a Ti metal plate serving as a substrate for BDD growth (Figure A) during the CVD process with different diborane concentrations in the gas phase (B/C ratio equals 2000, 5000, and 10 000). The Raman spectra differ from the typical one and show a narrow sp 3 band, a wide sp 2 band, and a signal attributed to the nanocrystalline diamond and C−H stretching vibrations.…”

Section: Diamond‐based Compositesmentioning

confidence: 99%

Nano‐engineered Diamond‐based Materials for Supercapacitor Electrodes: A Review

Siuzdak

Bogdanowicz

2017

Energy Tech

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Owing to the popularity of carbon‐based supercapacitors, diamond has been examined as a potential candidate for such devices with unique advantages such as a wide electrochemical potential window and stable capacitive behavior in both aqueous and non‐aqueous electrolytes. Moreover, its chemical stability in harsh environments at extreme applied potentials and currents provides unique opportunities for designing new supercapacitors. Owing to the intrinsic low surface area of diamond, it is necessary to increase the electrochemically active surface area or to produce diamond‐based composites, thereby ensuring capacitance improvement for the practical applications. According to previous literature reports, nano‐engineered diamond structures can achieve a specific capacitance values as high as 10 mF cm−2 with a specific energy of 10–100 Wh kg−1 in aqueous electrolyte. The present manuscript reviews the recent advances in this topic of research by highlighting the potentials and challenges of diamond‐based supercapacitors. Special attention is paid to the fabrication methods and electrochemical performance of particular material combinations in view of further application for supercapacitor construction.

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Preparation of TiO2/boron-doped diamond/Ta multilayer films and use as electrode materials for supercapacitors

Cited by 31 publications

References 41 publications

Designing 3D Multihierarchical Heteronanostructures for High-Performance On-Chip Hybrid Supercapacitors: Poly(3,4-(ethylenedioxy)thiophene)-Coated Diamond/Silicon Nanowire Electrodes in an Aprotic Ionic Liquid

Designing 3D Multihierarchical Heteronanostructures for High-Performance On-Chip Hybrid Supercapacitors: Poly(3,4-(ethylenedioxy)thiophene)-Coated Diamond/Silicon Nanowire Electrodes in an Aprotic Ionic Liquid

Diamond Supercapacitors: Towards Durable, Safe, and Biocompatible Aqueous-Based Energy Storage

Nano‐engineered Diamond‐based Materials for Supercapacitor Electrodes: A Review

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