2008
DOI: 10.1039/b805072d
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Preparation of self-supporting hierarchical nanostructured anatase/rutile composite TiO2 film

Abstract: Via the combination of an electrospinning method with a hydrothermal reaction, a large-scale cedar-like hierarchical nanostructured TiO(2) film with an anatase/rutile composite phase was fabricated.

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Cited by 77 publications
(42 citation statements)
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“…Synthesis of TiO 2 NR and Nanoribbon Films: A TiO 2 NR array on conducting glass electrodes was prepared by the hydrothermal method developed by Chen and co-workers with some modifications [45]. While preparing the manuscript, we noticed that a similar synthetic route to NRs was published recently [46].…”
Section: Methodsmentioning
confidence: 99%
“…Synthesis of TiO 2 NR and Nanoribbon Films: A TiO 2 NR array on conducting glass electrodes was prepared by the hydrothermal method developed by Chen and co-workers with some modifications [45]. While preparing the manuscript, we noticed that a similar synthetic route to NRs was published recently [46].…”
Section: Methodsmentioning
confidence: 99%
“…Among the three different crystal structures of TiO 2 , rutile, anatase, and brookite, rutile is the thermodynamically stable phase, whereas anatase has been generally accepted to have a higher photocatalytic activity than rutile owing to its anomalously large Born effective charge tensor as the result of the presence of enhanced Ti(3d states)-O(2p states) hybridization [25]. The photocatalytic activity of anatase TiO 2 can be greatly improved by mixing rutile nanostructures due to the mixed crystal effect [26,27]. Therefore, safe and simple formation of TiO 2 nanorod arrays with anatase or anatase/rutile structure is significant for their application in photovoltaic devices and photocatalysis.…”
Section: Introductionmentioning
confidence: 98%
“…These nanostructures provide interconnections of different functional elements. Branched nanostructures of semiconducting oxides such as ZnO [5], SnO 2 [6], In 2 O 3 [7], and TiO 2 [8] have been grown by different techniques and used in different applications. Among them, SnO 2 nanostructures are particularly important because of their outstanding applications such as Li-ion batteries [2] gas sensors [3], UV detectors [9], and field emitters [10].…”
Section: Introductionmentioning
confidence: 99%