Preparation of Organometallic Complexed Sugars:  Hetero Diels−Alder Reactivity of Tricarbonyl(formyltrimethylenemethane)- iron

Kleindl, Paul J.; Donaldson, William A.

doi:10.1021/jo970234+

“…360,361 Tricarbonyl(formyltrimethylenemethane)iron undergoes hetero-Diels-Alder reactions with dienes to yield deoxypyranosides tagged with the iron tricarbonyl manifold (Scheme 134). 362 A study has been made of the effect of ligand structure and acidity for a range of lanthanide catalysts used for the hetero-Diels-Alder reaction between crotonaldehyde and ethyl vinyl ether. 363 Similarly, a study of the effect of magnesium perchlorate on the competition between an intramolecular hetero-Diels-Alder and intramolecular ene reaction of 82 has been published.…”

Section: Hetero Diels-alder Reactionsmentioning

confidence: 99%

Cycloadditions in synthesis

Dell¹

1998

J. Chem. Soc., Perkin Trans. 1

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Iron: Organometallic ChemistryBased in part on the article Iron: Organometallic Chemistry by James R. Green which appeared in theEncyclopedia of Inorganic Chemistry, First Edition.

Paley¹

2005

Encyclopedia of Inorganic Chemistry

1

0

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Studies involving the preparation, reactivity, and properties of the organometallic complexes of iron (compounds possessing a FeC bond) have played a central role in the growth of organometallics as a major subdiscipline with chemistry. From the discovery of ferrocene in the 1950s to the present day, interest and research activity remain high. This entry provides a survey of this large and diverse area of organometallic chemistry, and is arranged by increasing hapticity of the organic ligand of interest that is bound to iron. Included are discussions of the chemistry of iron σ‐alkyl, acyl, alkynyl, and vinyl complexes, iron carbenes, η1‐ and η3‐allyl iron complexes, η2‐alkene and η4‐diene iron complexes, trimethylenemethane and cyclobutadiene complexes of iron, cationic iron pentadienyl, cyclohexadienyl, and arene complexes, and ferrocenes and heteroferrocenes.

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Iron: Organometallic ChemistryBased in part on the article Iron: Organometallic Chemistry by James R. Green which appeared in theEncyclopedia of Inorganic Chemistry, First Edition.

Paley

¹

2005

Encyclopedia of Inorganic and Bioinorganic Chemistry

1

0

View full text Add to dashboard Cite

Studies involving the preparation, reactivity, and properties of the organometallic complexes of iron (compounds possessing a FeC bond) have played a central role in the growth of organometallics as a major subdiscipline with chemistry. From the discovery of ferrocene in the 1950s to the present day, interest and research activity remain high. This entry provides a survey of this large and diverse area of organometallic chemistry, and is arranged by increasing hapticity of the organic ligand of interest that is bound to iron. Included are discussions of the chemistry of iron σ‐alkyl, acyl, alkynyl, and vinyl complexes, iron carbenes, η1‐ and η3‐allyl iron complexes, η2‐alkene and η4‐diene iron complexes, trimethylenemethane and cyclobutadiene complexes of iron, cationic iron pentadienyl, cyclohexadienyl, and arene complexes, and ferrocenes and heteroferrocenes.

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Preparation of Organometallic Complexed Sugars: Hetero Diels−Alder Reactivity of Tricarbonyl(formyltrimethylenemethane)- iron

Cited by 7 publications

References 28 publications

Cycloadditions in synthesis

Cycloadditions in synthesis

Iron: Organometallic ChemistryBased in part on the article Iron: Organometallic Chemistry by James R. Green which appeared in theEncyclopedia of Inorganic Chemistry, First Edition.

Iron: Organometallic ChemistryBased in part on the article Iron: Organometallic Chemistry by James R. Green which appeared in theEncyclopedia of Inorganic Chemistry, First Edition.

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