2015
DOI: 10.1016/j.jpowsour.2014.12.125
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Preparation of nickel nanowire arrays electrode for urea electro-oxidation in alkaline medium

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Cited by 160 publications
(77 citation statements)
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“…This rough surface is probably caused by the interaction between the Ni and the warmed KOH solution which was used to hydrolyze and dissolve the polycarbonate template. This conclusion was proved by the fact that when we employed the dichloromethane to dissolve the template, the surface of Ni nanowires turned out to be very smooth . The adoption of warmed KOH here brings about the increased roughness and hence improves the specific surface area of the Ni NAs electrode.…”
Section: Resultsmentioning
confidence: 87%
See 1 more Smart Citation
“…This rough surface is probably caused by the interaction between the Ni and the warmed KOH solution which was used to hydrolyze and dissolve the polycarbonate template. This conclusion was proved by the fact that when we employed the dichloromethane to dissolve the template, the surface of Ni nanowires turned out to be very smooth . The adoption of warmed KOH here brings about the increased roughness and hence improves the specific surface area of the Ni NAs electrode.…”
Section: Resultsmentioning
confidence: 87%
“…This conclusion was proved by the fact that when we employed the dichloromethane to dissolve the template, the surface of Ni nanowires turned out to be very smooth. [10] The adoption of warmed KOH here brings about the increased roughness and hence improves the specific surface area of the Ni NAs electrode.…”
Section: Physicochemical Characterizationmentioning
confidence: 99%
“…current density = 700 mA cm -2 mg -1 vs. at 0.7 V SCE). Guo et al [89] described a method for the preparation of nickel nanowire arrays (NWAs) by electrodeposition on a polycarbonate template. The electrodes exhibited lower onset potentials for urea electrolysis in an alkaline medium compared to flat Ni electrodes.…”
Section: Anode Materialsmentioning
confidence: 99%
“…3 Recently, urea is also explored as potential hydrogen storage materials, and monitoring of urea concentration may be important in developing highly performing energy storage and conversion systems. 2 Many sensing platforms are based on the use of enzyme to hydrolyze urea for the release of NH 4+ , HCO 3− , and OH − ions. This method can suffer the difficulties associated with enzyme immobilization technique and stability problems caused by denaturation of enzyme.…”
mentioning
confidence: 99%
“…3 However, problems related to degradation and expansion of the Ni based catalyst structure during the oxidation still exist. 4 Moreover, nickel's reaction with dissolved oxygen in aerated alkaline solution may result in potential variation driven by formation of Ni(OH) 2 and NiOOH. Such change in concentration of OH − anions is a dominant factor of Ni based catalyst to examine physiological measurement.…”
mentioning
confidence: 99%