A novel La/O coādoped SnS oxysulfide catalyst (labeled SnLaOS) with heterovalent tin states and sulfur vacancy defects is successfully synthesized for effective catalytic reduction of toxic organics heavy metal ions with NaBH4 in the dark. La/O coādoped and hydrogen peroxideādriven SnLaOS catalyst with suitable heterovalent Sn2+/Sn4+ states and sulfur vacancy defects exhibited excellent catalytic reduction capability. The 100Ā mL 20Ā ppm of 4ānitrophenol (4āNP) and 50Ā ppm of rhodamineāB (RhB), methylene blue (MB), methyl orange (MO), and Cr(VI) solution are entirely reduced by 5Ā mg SnLaOSā3 within 10, 12, 12, 16, and 14Ā min, respectively, with durable stability. Synergistic transition metal La3+ācation and O2āāanion coādoped SnS adjusted the energy bandgap and introduced sulfur vacancy defects, and the hydrogen peroxideādriven regulated the SnLaOS with suitable Sn4+/Sn2+ states ratio. The sulfur vacancies in SnLaOS provide active sites for adsorbed proton for pollutants reduction, and heterovalent Sn2+/Sn4+ states in SnLaOS facilitates electrons efficient transfer through electron hopping between Sn2+ and Sn4+ for pollutants reduction. This study provides a novel efficient catalyst for the water pollutants treatment.