“…In order to enhance the interfacial charge-transfer efficiency and utilize a wider spectral range of solar energy, the TiO 2 catalyst has been modified by ion doping 19,20 and manipulating the nanomaterial composition. 21,22 Rare earth (RE) ion dopants, such as Ce, 23 La, 24 Er 25 and Pr, 26 have shown unique enhancement effects, resulting from the orbital hybridization of 4f electrons. Positive effects of 4f electron orbital hybridization on the photocatalytic activities of TiO 2 were reported previously.…”