2008
DOI: 10.1080/00914030802153397
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Preparation of BPA Epoxy Resin/POSS Nanocomposites and Nonisothermal Co-curing Kinetics with MeTHPA

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Cited by 11 publications
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“…Together with IR and NMR studies, the cage species present in the mixture, including T 8 derivatives, were proposed to be more stable than the ladder structures formed . LC/MS has been used to characterize the products obtained from cohydrolysis of MeSi(OEt) 3 and CH 2 (O)CHCH 2 O(CH 2 ) 3 Si(MeO) 3 and shows that T 8 derivatives T 8 Me 8− n [(CH 2 ) 3 OCH 2 CH(O)CH 2 ] n (where n = 4 or 6) are formed along with T 9 and T 10 compounds . Electrospray mass spectrometry has also been used in a detailed study of how T 8 (OH) 8 and other silicate polyhedra are built up in solution from smaller silicate fragments. Methoxylation of the cube to give T 8 (OH) 7 OMe can be observed to occur either by reaction with the methanol solvent or by breakdown of the Me 4 N + template ion .…”
Section: Physical Properties Of Poss Compoundsmentioning
confidence: 99%
“…Together with IR and NMR studies, the cage species present in the mixture, including T 8 derivatives, were proposed to be more stable than the ladder structures formed . LC/MS has been used to characterize the products obtained from cohydrolysis of MeSi(OEt) 3 and CH 2 (O)CHCH 2 O(CH 2 ) 3 Si(MeO) 3 and shows that T 8 derivatives T 8 Me 8− n [(CH 2 ) 3 OCH 2 CH(O)CH 2 ] n (where n = 4 or 6) are formed along with T 9 and T 10 compounds . Electrospray mass spectrometry has also been used in a detailed study of how T 8 (OH) 8 and other silicate polyhedra are built up in solution from smaller silicate fragments. Methoxylation of the cube to give T 8 (OH) 7 OMe can be observed to occur either by reaction with the methanol solvent or by breakdown of the Me 4 N + template ion .…”
Section: Physical Properties Of Poss Compoundsmentioning
confidence: 99%