Preparation of boron-doped hydrothermal carbon from glucose for carbon paste electrode

Kalijadis, Ana; Đorđević, Jelena; Trtić-Petrović, Tatjana; Vukčević, Marija; Popović, Maja; Maksimović, Vesna; Rakocevic, Zlatko; Laušević, Ž.

doi:10.1016/j.carbon.2015.08.016

Cited by 42 publications

(36 citation statements)

References 63 publications

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“…In Figure 3(c), after analyzing the high resolution spectra of BC sample in the range of 180-196 eV. The high resolution B 1s peak at 191.6 eV was evidence for the existence of B species [39,46]. The splitted two peaks at 191.2 eV and 192.6 eV took 0.58 at% and 1.55 at%, respectively, belonging to B 1s of B-C 3 , B-C 2 O with different bonding species [18].…”

Section: X-ray Photoelectron Spectroscopy (Xps) Xps Was Mea-mentioning

confidence: 97%

“…The top peak at ca. 284.4 eV was most likely ascribed to the sp 2 -C of C=C double bonds [15][16][17][18]27]. However, the C 1s of B-C-X could not be observed due to the low percentage.…”

Section: X-ray Photoelectron Spectroscopy (Xps) Xps Was Mea-mentioning

confidence: 99%

“…According to the fact of boron-doping ratio, the second peak at 285.5 eV was partially ascribed to the C-B bond which was buried in the second peak with other bond species. Partial of the second peak and the last one was defined as the signal of C-O/C=O bonds [16,17]. These C of BC took corresponding ratio as 56.94 at%, 21.29 at%, and 5.2 at%, respectively.…”

Section: X-ray Photoelectron Spectroscopy (Xps) Xps Was Mea-mentioning

confidence: 99%

“…Various precursors with different heteroelement species [15][16][17][18] or increased amount of heteroatoms [4,9,10,[19][20][21][22] including N [20,[23][24][25], P [4,[15][16][17][18][26][27][28][29][30], S [31][32][33][34], Si [9,21,22], and Sn-doping [7,35,36] have been explored to upgrade the carbonaceous anodic materials for Li + ion storage due to their great high theoretical specific capacity of Li + ion storage. Although boron could effectively adjust the lattice defect related to the structure disorder of carbon materials, there are quite few reports on boron-doped carbon as Li + ion storage anode [37].…”

Section: Introductionmentioning

confidence: 99%

“…Although boron could effectively adjust the lattice defect related to the structure disorder of carbon materials, there are quite few reports on boron-doped carbon as Li + ion storage anode [37]. Previous reported boron-doped carbons were investigated as the cathode catalysts for Na-O batteries [38], carbon paste electrode [39], supercapacitor [40][41][42][43], and H 2 physisorption [44] with improved versatile characteristics including oxidation activity and electrochemical performance. One important reason for the lack research of boron-doped carbon is ascribed to the less of boron sources except for the reported BF 3 [45,46], HBO 3 [38,40], and BCl 3 [47].…”

Section: Introductionmentioning

confidence: 99%

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Boron-Doped Carbon Nano-/Microballs from Orthoboric Acid-Starch: Preparation, Characterization, and Lithium Ion Storage Properties

Chen

2018

Journal of Nanomaterials

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A boron-doped carbon nano-/microballs (BC) was successfully obtained via a two-step procedure including hydrothermal reaction (180 ∘ C) and carbonization (800 ∘ C) with cheap starch and H 3 BO 3 as the carbon and boron source. As a new kind of boron-doped carbon, BC contained 2.03 at% B-content and presented the morphology as almost perfect nano-/microballs with different sizes ranging from 500 nm to 5 m. Besides that, due to the electron deficient boron, BC was explored as anode material and presented good lithium storage performance. At a current density of 0.2 C, the first reversible specific discharge capacity of BC electrode reached as high as 964.2 mAh g -1 and kept at 699 mAh g -1 till the 11th cycle. BC also exhibited good cycle ability with a specific capacity of 356 mAh g -1 after 79 cycles at a current density of 0.5 C. This work proved to be an effective approach for boron-doped carbon nanostructures which has potential usage for lithium storage material.

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Section: X-ray Photoelectron Spectroscopy (Xps) Xps Was Mea-mentioning

confidence: 97%

“…The top peak at ca. 284.4 eV was most likely ascribed to the sp 2 -C of C=C double bonds [15][16][17][18]27]. However, the C 1s of B-C-X could not be observed due to the low percentage.…”

Section: X-ray Photoelectron Spectroscopy (Xps) Xps Was Mea-mentioning

confidence: 99%

Section: X-ray Photoelectron Spectroscopy (Xps) Xps Was Mea-mentioning

confidence: 99%

Section: Introductionmentioning

confidence: 99%

Section: Introductionmentioning

confidence: 99%

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Boron-Doped Carbon Nano-/Microballs from Orthoboric Acid-Starch: Preparation, Characterization, and Lithium Ion Storage Properties

Chen

2018

Journal of Nanomaterials

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Electrocatalytic Activity of Ionic‐Liquid‐Derived Porous Carbon Materials for the Oxygen Reduction Reaction

et al. 2018

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Carbon materials, prepared by using different methods with ionic liquids, are compared as electrocatalysts for the oxygen reduction reaction (ORR). Materials were synthesized through the hydrothermal carbonization of glucose and by using the same method in the presence of 1‐butyl‐3‐methylimidazolium methanesulfonate [bmim][MeSO3] as an additive. Another two carbon‐based materials were prepared by using ionic‐liquid‐based methods: ionothermal carbonization of glucose using [bmim][MeSO3] as a recyclable medium for the carbonization reaction and by direct carbonization of the ionic liquid in a one‐step method using [bmim][MeSO3] as the precursor for N‐ and S‐doped porous carbon (Carb‐IL). Characterization results showed the possibility of morphology and porosity control by using [bmim][MeSO3]. All materials were subsequently tested for the ORR in alkaline media. Carb‐IL showed enhanced and stable electrocatalytic ORR activity, even in the presence of methanol, ethanol, and borohydride, opening the possibility for its application in fuel cells.

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Tellurite Carbon Paste Sensors: Microscopic Analysis Provides New Insights on the Nature of the Interaction Between the Ionophore and Analytical Species

et al. 2017

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In this work, scanning electron microscopy (SEM) was used for the characterization of chemically modified carbon paste sensors (CMCPSs), with the aim of understanding their chemical and electrochemical properties. The work also provides a microscopic study on the role of the binder, type of carbon, amount and nature of modifier, composition of the carbon paste and its impact on the electrochemical performance of the sensor. In addition, energy dispersive X‐ray spectroscopy (EDX) was utilized for the direct observation of the interaction between the chemical modifier and the carbon paste. This has enabled the fabrication of new sensitive and selective chemically modified carbon paste sensors that were successfully applied for the detection of tellurite ions in pure solutions, environmental and biological samples. This work provides new insights on the rational design and integration of carbon paste sensors for a variety of applications.

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Preparation of boron-doped hydrothermal carbon from glucose for carbon paste electrode

Cited by 42 publications

References 63 publications

Boron-Doped Carbon Nano-/Microballs from Orthoboric Acid-Starch: Preparation, Characterization, and Lithium Ion Storage Properties

Boron-Doped Carbon Nano-/Microballs from Orthoboric Acid-Starch: Preparation, Characterization, and Lithium Ion Storage Properties

Electrocatalytic Activity of Ionic‐Liquid‐Derived Porous Carbon Materials for the Oxygen Reduction Reaction

Tellurite Carbon Paste Sensors: Microscopic Analysis Provides New Insights on the Nature of the Interaction Between the Ionophore and Analytical Species

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