Preparation of Aliphatic Peroxyacids

Phillips, Benjamin; Starcher, Paul S.; Ash, Bertrand D.

doi:10.1021/jo01106a001

Cited by 41 publications

(19 citation statements)

References 2 publications

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“…14,15 However, weak carboxylic acids, such as acetic acid or benzoic acid, require a strong acid catalyst for conversion to percarboxylic acid. 16,17 As alternatives to carboxylic acids, carboxylic anhydrides have been used for the in situ production of percarboxylic acid with H 2 O 2 . 18,19 Acetic anhydride, 20 triuoroacetic anhydride, 21,22 maleic anhydride, 23,24 and phthalic anhydride 25 have been used as mediators in oxidation reactions based on H 2 O 2 .…”

Section: Introductionmentioning

confidence: 99%

Recyclable anhydride catalyst for H₂O₂ oxidation: N-oxidation of pyridine derivatives

et al. 2020

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The catalytic efficiency and recyclability of poly(maleic anhydride-alt-1-octadecene) (Od-MA) and poly(maleic anhydride-alt-1-isobutylene) (Bu-MA) were evaluated for use in the development of a metalfree, reusable catalyst for the oxidation of pyridines to pyridine N-oxides in the presence of H 2 O 2 . The Od-MA catalyst was easily recovered via filtration with recovery yields exceeding 99.8%. The catalyst retained its activity after multiple uses and did not require any treatment for reuse. The Od-MA and H 2 O 2 catalytic system described herein is eco-friendly, operationally simple, and cost-effective; thus, it is industrially applicable. Od-MA and H 2 O 2 could potentially be used in place of percarboxylic acid as an oxidant in a wide range of oxidation reactions.

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Section: Introductionmentioning

confidence: 99%

Recyclable anhydride catalyst for H₂O₂ oxidation: N-oxidation of pyridine derivatives

et al. 2020

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“…The greater reactivity in acetic acid may be caused by the formation of peracid, which is a stronger oxidant than H 2 O 2 . [16,17] Finally, we investigated the reusability of Amberlyst 15. Under solvent-free conditions, the yield of benzoic acid decreased on the regenerated catalyst, and 75% yield of benzoic acid was obtained in the third reaction runs (Table 1, entry 21).…”

Section: Resultsmentioning

confidence: 99%

Sulfonic Acid Resin–Catalyzed Oxidation of Aldehydes to Carboxylic Acids by Hydrogen Peroxide

Yang

Tang

et al. 2013

Synthetic Communications

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“…(1) CH 3 CO 3 H was synthesized with a known technique [14]. Injection and metering of CH 3 CO 3 H was carried out with the help of a sample reservoir (4) and Figure 1 Scheme of major units of setup.…”

Section: Resultsmentioning

confidence: 99%

Reactions of CH₃O₂ radicals on solid surface

Manucharova

Tsarukyan

Vardanyan

2004

Int J of Chemical Kinetics

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The reaction probability of CH 3 O 2 radicals with NO 2 , CH 4 , C 3 H 6 , and CH 3 CHO on the solid surface of KCl in flow at low pressure and temperature range of 297-353 K has been studied. The chosen conditions allowed excluding homogeneous interaction of radicals. The heterogeneous radical decay of peracetic acid served as a source of CH 3 O 2 radicals.On the basis of ESR measurements of CH 3 O 2 radicals with the above-mentioned compounds, a heterogeneous reaction mechanism has been identified.The reactivity of NO 2 was greatest for the compounds studied. The effective activation energy was evaluated to be 10.4 ± 0.8 kJ/mol for the reaction of RO 2 radicals with NO 2 and −21.3 ± 2.8 kJ/mol for methane. C

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Preparation of Aliphatic Peroxyacids

Cited by 41 publications

References 2 publications

Recyclable anhydride catalyst for H₂O₂ oxidation: N-oxidation of pyridine derivatives

Recyclable anhydride catalyst for H₂O₂ oxidation: N-oxidation of pyridine derivatives

Sulfonic Acid Resin–Catalyzed Oxidation of Aldehydes to Carboxylic Acids by Hydrogen Peroxide

Reactions of CH₃O₂ radicals on solid surface

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Preparation of Aliphatic Peroxyacids

Cited by 41 publications

References 2 publications

Recyclable anhydride catalyst for H2O2 oxidation: N-oxidation of pyridine derivatives

Recyclable anhydride catalyst for H2O2 oxidation: N-oxidation of pyridine derivatives

Sulfonic Acid Resin–Catalyzed Oxidation of Aldehydes to Carboxylic Acids by Hydrogen Peroxide

Reactions of CH3O2 radicals on solid surface

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Recyclable anhydride catalyst for H₂O₂ oxidation: N-oxidation of pyridine derivatives

Recyclable anhydride catalyst for H₂O₂ oxidation: N-oxidation of pyridine derivatives

Reactions of CH₃O₂ radicals on solid surface