Preparation of Acidic Electrolyzed Water by a RuO₂@TiO₂ Electrode with High Selectivity for Chlorine Evolution and Its Sterilization Effect

Abstract

The food hygiene problems caused by bacterial biofilms in food processing equipment are directly related to human life safety and health. Therefore, it is of great strategic significance to study new food sterilization technology. An acidic electrolyzed water (AEW) disinfectant is an electrochemical sterilization technology which has the characteristics of wide adaptability, high efficiency, and environmental friendliness. However, since the sterilization efficiency of AEW for biofilms is not ideal, it is necessary to increase the available chlorine content (ACC) in AEW. A feasible method to increase the ACC is by increasing the chlorine evolution reaction (CER) selectivity of the electrode for AEW preparation. In this paper, the RuO 2 @TiO 2 electrode was prepared by thermal decomposition combined with high-vacuum magnetron sputtering. Compared with the oxygen evolution reaction (OER) activity of an ordinary RuO 2 electrode, the OER activity of the RuO 2 @TiO 2 electrode is significantly reduced. However, the CER activity of the RuO 2 @TiO 2 electrode is close to the OER activity of RuO 2 . The CER mechanism of the RuO 2 @TiO 2 electrode is the second electron transfer, and the OER mechanism is the formation and transformation of OH ads . The potential difference between the CER and OER of the RuO 2 @TiO 2 electrode is 174 mV, which is 65 mV higher than that of the RuO 2 electrode, so the selectivity of the CER of the RuO 2 @TiO 2 electrode is remarkably improved. During the preparation of AEW, the ACC obtained with the RuO 2 @TiO 2 electrode is 1.7 times that obtained with the RuO 2 electrode. In the sterilization experiments on Escherichia coli and Bacillus subtilis biofilms, the logarithmic killing values of AEW prepared the by RuO 2 @TiO 2 electrode are higher than those of AEW prepared by the RuO 2 electrode.

Improvement in the chlorine evolution activity of an SnOx@IrO2–Ta2O5 electrode and its application in the electrolysis of an extremely dilute chlorine-containing solution

“…37 In order to verify the calculation results, our research group prepared the TiO 2 /RuO 2 electrode by magnetron sputtering combined with the thermal decomposition method, which greatly improved the selectivity of CER. 55 IrO 2 -Ta 2 O 5 electrode is a well-known DSA electrode that is often used in the electrochemical chlorine evolution reaction. In order to further improve the CER activity and selectivity of the IrO 2 -Ta 2 O 5 electrode, the SnO x -modified IrO 2 -Ta 2 O 5 electrode (SnO x @IrO 2 -Ta 2 O 5 ) was prepared in this paper.…”

“…37 In order to verify the calculation results, our research group prepared the TiO 2 /RuO 2 electrode by magnetron sputtering combined with the thermal decomposition method, which greatly improved the selectivity of CER. 55…”