Preparation of 2-C- and 3-C-cyano-2-enopyranoside derivatives and their epoxidation

Sakakibara, Tohru; Narumi, Shinya; Matsuo, Ichiro; Okada, Saeko; Nakamura, Takanori

doi:10.1016/j.carres.2007.07.008

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Reação De Epoxidação1

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“…Outros exemplos de reação de epoxidação à dupla ligação de O-glicosideos 2,3-insaturados são descritos na literatura. 126,127…”

Section: Reação De Epoxidaçãounclassified

O-Glicosídeos 2,3-Insaturados: Aplicações, Rearranjo De Ferrier E Reações

et al. 2018

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APPLICATIONS, FERRIER REARRANGEMENT AND REACTIONS. In carbohydrate chemistry, the O-glycoside is an organic molecule in which sugar is bound to another functional group via a glycosidic bond. In the last few years, considerable progress has been made in the synthesis and applications of O-glycosides. Despite their challenging chemistry, due to their versatility, O-glycosides play a pivotal role the development of the chemistry of novel materials and bioactive molecules. This review summarizes recent developments, in the last twenty years, about the Ferrier rearrangement reaction involving synthesis, mechanistic proposal and application of 2,3-unsaturated O-glycosides.

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“…Outros exemplos de reação de epoxidação à dupla ligação de O-glicosideos 2,3-insaturados são descritos na literatura. 126,127…”

Section: Reação De Epoxidaçãounclassified