Preparation, characterization and Cr(VI) adsorption evaluation of NaOH-activated carbon produced from Date Press Cake; an agro-industrial waste

Norouzi, Samira; Heidari, Mohsen; Alipour, Vali; Rahmanian, Omid; Fazlzadeh, Mehdi; Mohammadi‐Moghadam, Fazel; Nourmoradi, Heshmatollah; Goudarzi, Babak; Dindarloo, Kavoos

doi:10.1016/j.biortech.2018.02.106

Cited by 232 publications

(60 citation statements)

References 45 publications

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“…The equilibrium adsorption capacity was 74.38 mg/g. The pseudo first-order (PFO), pseudo second-order (PSO) and Elovich models were applied to the experimental data to evaluate the adsorption kinetics, in order to understand the controlling mechanisms of the Cr(VI) sorption on SLACM [7,27]. These models are given as the following equations, respectively.…”

Section: Adsorption Kineticsmentioning

confidence: 99%

“…The effluents from a variety of industrial processes such as metallurgy, petroleum refining, batteries, and electroplating are responsible for introducing these heavy metals into aquatic environments [4,5]. These heavy metals include chromium (Cr), cadmium (Cd), lead (Pb), mercury (Hg), and other heavy metal ions and compounds [6][7][8]. These heavy metals are insistent and non-degradable in nature, but they are soluble in the aquatic environment; therefore, they can be easily absorbed into living cells [9].…”

Section: Introductionmentioning

confidence: 99%

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Activated Carbon Microsphere from Sodium Lignosulfonate for Cr(VI) Adsorption Evaluation in Wastewater Treatment

Yang

Xing

et al. 2020

Polymers

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In this study, activated carbon microsphere (SLACM) was prepared from powdered sodium lignosulfonate (SL) and polystyrene by the Mannich reaction and ZnCl2 activation, which can be used to remove Cr(VI) from the aqueous solution without adding any binder. The SLACM was characterized and the batch experiments were conducted under different initial pH values, initial concentrations, contact time durations and temperatures to investigate the adsorption performance of Cr(VI) onto SLACM. The results indicated that the SLACM surface area and average pore size were 769.37 m2/g and 2.46 nm (the mesoporous material), respectively. It was found that the reduced initial pH value, the increased temperature and initial Cr(VI) concentration were beneficial to Cr(VI) adsorption. The maximum adsorption capacity of Cr(VI) on SLACM was 227.7 mg/g at an initial pH value of 2 and the temperature of 40 °C. The adsorption of SLACM for Cr(VI) mainly occurred during the initial stages of the adsorption process. The adsorption kinetic and isotherm experimental data were thoroughly described by Elovich and Langmuir models, respectively. SL could be considered as a potential raw material for the production of activated carbon, which had a considerable potential for the Cr(VI) removal from wastewater.

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Section: Adsorption Kineticsmentioning

confidence: 99%

Section: Introductionmentioning

confidence: 99%

Activated Carbon Microsphere from Sodium Lignosulfonate for Cr(VI) Adsorption Evaluation in Wastewater Treatment

Yang

Xing

et al. 2020

Polymers

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“…The removal rate of Cr(VI) by PPy/HMSNs was higher than those of PPy and HMSNs at the range of pH 2−10. The removal rate decreased gradually with the increase in pH because the main chemical species of Cr(VI)-based ionic compounds were changed by pH (pH 2 [25][26][27]. Furthermore, the zero-potential point of PPy/HMSNs was observed at pH 5.4, as shown in Figure S9.…”

Section: Resultsmentioning

confidence: 93%

Removal of Cr(VI) from Aqueous Solution by Polypyrrole/Hollow Mesoporous Silica Particles

Gao

Liu

et al. 2020

Nanomaterials

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The removal of Cr(VI) in wastewater plays an important role in human health and environment. In this work, polypyrrole/hollow mesoporous silica particle (PPy/HMSNs) adsorbents have been newly synthesized by in-situ polymerization, which prevent the aggregation of pyrrole in the process of polymerization and exhibit highly selective and powerful adsorption ability for Cr(VI). The adsorption process was in good agreement with the quasi-second-order kinetic model and the Langmuir isotherm model. And the maximum adsorption capacity of Cr(VI) was 322 mg/g at 25 °C. Moreover, the removal rate of Cr(VI) by PPy/HMSNs was ~100% in a number of binary systems, such as Cl−/Cr(VI), NO3−/Cr(VI), SO42−/Cr(VI), Zn2+/Cr(VI), Fe3+/Cr(VI), Sn4+/Cr(VI), and Cu2+/Cr(VI). Thus, the PPy/HMSNs adsorbents have great potential for the removal of Cr(VI) in wastewater.

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“…Biochar is an organic‐based material with high durability and structural integrity and its cost could be minimized when prepared from cheap agro‐industrial wastes. Recently, a biochar (carbonized material) with yield value (product to raw material weight ratio) of 45.5% was produced from Date Press Cake (DPC) . DPC is a caked by‐product of filter press units in Date processing industries .…”

Section: Resultsmentioning

confidence: 99%

Mathematical modeling and sensitivity analysis of xylene removal in a scoria‐compost biofilter

Heidari

Rahimi

Amin

et al. 2019

Env Prog and Sustain Energy

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Mathematical modeling of biofiltration systems improves our understanding and design of such complex systems. This study focused on the theoretical and technical aspects of the modeling of xylene biofiltration in the absence and presence of a nonionic surfactant. In this regard, a mathematical model was developed based on mass balance principles in gas and biofilm phases. The developed model was calibrated and validated using the experimental data obtained from a lab‐scale scoria‐compost biofilter, which operated for 151 days in the absence and presence of Tween‐20, a nonionic surfactant. First, the model was calibrated using the experimental data obtained at empty bed retention time (EBRT) of 90 s and then validated with the data obtained at two other EBRTs. The biofilter provided maximum elimination capacities (ECmax) of 97.5 and 93.6 g m−3 hr−1, respectively, in the absence and presence of the surfactant at EBRT of 90 s. The corresponding predicted ECmax values were 99.9 and 95.7 g m−3 hr−1, respectively. Both model output and experimental data revealed that the nonionic surfactant improved the performance of the biofilter at moderate inlet loading rates. Various statistical measures, including fractional bias, average absolute relative error, and coefficient of determination (R2), showed good agreement between experimental data and estimated model predictions. Sensitivity analysis of the model showed that the specific surface area and bioreactor length affected strongly the results of the model. In general, the results of this study would in turn form the design basis for engineering purposes.

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Preparation, characterization and Cr(VI) adsorption evaluation of NaOH-activated carbon produced from Date Press Cake; an agro-industrial waste

Cited by 232 publications

References 45 publications

Activated Carbon Microsphere from Sodium Lignosulfonate for Cr(VI) Adsorption Evaluation in Wastewater Treatment

Activated Carbon Microsphere from Sodium Lignosulfonate for Cr(VI) Adsorption Evaluation in Wastewater Treatment

Removal of Cr(VI) from Aqueous Solution by Polypyrrole/Hollow Mesoporous Silica Particles

Mathematical modeling and sensitivity analysis of xylene removal in a scoria‐compost biofilter

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