2016
DOI: 10.1016/j.jallcom.2016.05.330
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Preparation and thermoelectric properties of annealed CoSb and CoSb 2 thin films deposited through RF co-sputtering

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Cited by 13 publications
(6 citation statements)
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“…Within the intermetallic class, transition metal based binary and ternary antimonides have shown remarkable properties in the context of their applications in thermoelectrics, lithium/sodium ion batteries, electrochemical performance etc. [1][2][3][4][5][6] Binary antimonides, and FeSb in particular, have been observed to show enhanced catalytic and electrochemical performance as compared to their constituent elements. [7][8][9] Recently, FeSb nanoparticles embedded in nitrogen-doped carbon layers were shown to exhibit excellent activity and stability to the ORR (oxygen reduction reaction) and OER (oxygen evolution reaction) in alkaline medium.…”
Section: Introductionmentioning
confidence: 99%
“…Within the intermetallic class, transition metal based binary and ternary antimonides have shown remarkable properties in the context of their applications in thermoelectrics, lithium/sodium ion batteries, electrochemical performance etc. [1][2][3][4][5][6] Binary antimonides, and FeSb in particular, have been observed to show enhanced catalytic and electrochemical performance as compared to their constituent elements. [7][8][9] Recently, FeSb nanoparticles embedded in nitrogen-doped carbon layers were shown to exhibit excellent activity and stability to the ORR (oxygen reduction reaction) and OER (oxygen evolution reaction) in alkaline medium.…”
Section: Introductionmentioning
confidence: 99%
“…20 Therefore, many studies on the synthesis of high performance thin films, including CoSb 3 films, have been investigated. [21][22][23][24][25][26] For example, A. Ahmed et al 27 obtained a power factor of 7.92 mW m K −2 for the CoSb 2 -containing mixed phase thin film and 1.26 mW m K −2 for the stoichiometric CoSb 3 thin film. However, TE properties of CoSb 3 thin films remain lower than those of bulk materials due to the difficulty of controlling precisely the composition of the thin films.…”
Section: Introductionmentioning
confidence: 99%
“…The microstructure, composition, crystal structure and orientation of the thin films were evaluated by high resolution field emission scanning electron microscopy (FE-SEM), energy dispersive X-ray spectroscopy (EDS) and X-ray diffraction (XRD), respectively. The details of the characterization methods have been published elsewhere 7 , 12 .…”
Section: Methodsmentioning
confidence: 99%
“…Recently, attempts have been made to improve the thermoelectric efficiency of materials based on approaches such as carrier concentration optimization using impurities 6 8 , band structure modifications 8 , and lattice thermal conductivity reduction 3 , 9 . ZT values can be significantly improved in low-dimensional materials due to the stronger influence of quantum confinement effects and phonon scattering, which enable us to enhance the Seebeck coefficient and decrease the thermal conductivity, respectively 2 4 , 10 12 .…”
Section: Introductionmentioning
confidence: 99%