Abstract:Sodium alginate graft poly (acrylic acid‐co‐2‐acrylamide‐2‐methyl propane sulfonic acid)/graphene oxide (SA‐g‐P(AA‐co‐AMPS)/GO) hydrogel composite is prepared. The composite is characterized by infrared (IR) spectroscopy, X‐ray diffraction (XRD), high‐resolution scanning electron microscope (HRSEM), and differential scanning calorimetry (DSC). The swelling properties of the composite are investigated. GO acts as part of the cross‐linking points, which improves the swelling property of the composite. Maximal am… Show more
“…For a better view of the rough appearance of the surfaces, we have chosen to present images captured at the magnifications of 1000 (a2 and b2) and 5000 (a3 and b3). The increased sizes of crack-like structures that more space for solution Surfaces presented in Figure 15a1,b1 and Figure 16a1,b1 are rugged and loose with uneven interspaces, favorable for water molecules to get inside [54,55], an aspect that correlates with the high degrees of absorption in both types of solutions. For a better view of the rough appearance of the surfaces, we have chosen to present images captured at the magnifications of 1000 (a2 and b2) and 5000 (a3 and b3).…”
Section: Morphological Characterizationmentioning
confidence: 96%
“…The increased sizes of crack-like structures that provide more space for solution In Figures 15 and 16 are presented SEM micrographs of H2R1-D1 and H1R2-D2 hydrogels dried after the fourth absorption-release cycle in both types of aqueous solution with nutrients. Surfaces presented in Figures 15a1,b1 and 16a1,b1 are rugged and loose with uneven interspaces, favorable for water molecules to get inside [54,55], an aspect that correlates with the high degrees of absorption in both types of solutions. For a better view of the rough appearance of the surfaces, we have chosen to present images captured at the magnifications of 1000 (a2 and b2) and 5000 (a3 and b3).…”
Section: Morphological Characterizationmentioning
confidence: 97%
“…For a better view of the rough appearance of the surfaces, we have chosen to present images captured at the magnifications of 1000 (a2 and b2) and 5000 (a3 and b3). The increased sizes of crack-like structures that provide more space for solution penetration correlated with the high degree of absorption that can be seen [54,55].…”
Being both a cause and a victim of water scarcity and nutrient deficiency, agriculture as a sustainable livelihood is dependent now on finding new suport solutions. Biodegradable hydrogels usage as soil conditioners may be one of the most effective solutions for irrigation efficiency improvement, reducing the quantity of soluble fertilizers per crop cycle and combating pathogens, due to their versatility assured by both obtaining method and properties. The first goal of the work was the obtaining by electron beam irradiation and characterization of some Sodium Alginate-g-Acrylamide/Acrylic Acid hydrogels, the second one being the investigation of their potential use as a soil conditioner by successive experiments of absorption and release of two different aqueous nutrient solutions. Alginate-g-Acrylamide/Acrylic Acid hydrogels were obtained by electron beam irradiation using the linear accelerator ALID 7 at 5.5 MeV at the irradiation doses of 5 and 6 kGy. For this were prepared monomeric solutions that contained 1 and 2% sodium alginate, acrylamide and acrylic acid in ratios of 1:1 and 1.5:1, respectively, for the obtaining of materials with hybrid properties derived from natural and synthetic components. Physical, chemical, structural and morphological characteristics of the obtained hydrogels were investigated by specific analysis using swelling, diffusion and network studies and Fourier Transform Infrared Spectroscopy and Scanning Electron Microscopy. Four successive absorption and release experiments of some synthetic and natural aqueous solutions with nutrients were performed.
“…For a better view of the rough appearance of the surfaces, we have chosen to present images captured at the magnifications of 1000 (a2 and b2) and 5000 (a3 and b3). The increased sizes of crack-like structures that more space for solution Surfaces presented in Figure 15a1,b1 and Figure 16a1,b1 are rugged and loose with uneven interspaces, favorable for water molecules to get inside [54,55], an aspect that correlates with the high degrees of absorption in both types of solutions. For a better view of the rough appearance of the surfaces, we have chosen to present images captured at the magnifications of 1000 (a2 and b2) and 5000 (a3 and b3).…”
Section: Morphological Characterizationmentioning
confidence: 96%
“…The increased sizes of crack-like structures that provide more space for solution In Figures 15 and 16 are presented SEM micrographs of H2R1-D1 and H1R2-D2 hydrogels dried after the fourth absorption-release cycle in both types of aqueous solution with nutrients. Surfaces presented in Figures 15a1,b1 and 16a1,b1 are rugged and loose with uneven interspaces, favorable for water molecules to get inside [54,55], an aspect that correlates with the high degrees of absorption in both types of solutions. For a better view of the rough appearance of the surfaces, we have chosen to present images captured at the magnifications of 1000 (a2 and b2) and 5000 (a3 and b3).…”
Section: Morphological Characterizationmentioning
confidence: 97%
“…For a better view of the rough appearance of the surfaces, we have chosen to present images captured at the magnifications of 1000 (a2 and b2) and 5000 (a3 and b3). The increased sizes of crack-like structures that provide more space for solution penetration correlated with the high degree of absorption that can be seen [54,55].…”
Being both a cause and a victim of water scarcity and nutrient deficiency, agriculture as a sustainable livelihood is dependent now on finding new suport solutions. Biodegradable hydrogels usage as soil conditioners may be one of the most effective solutions for irrigation efficiency improvement, reducing the quantity of soluble fertilizers per crop cycle and combating pathogens, due to their versatility assured by both obtaining method and properties. The first goal of the work was the obtaining by electron beam irradiation and characterization of some Sodium Alginate-g-Acrylamide/Acrylic Acid hydrogels, the second one being the investigation of their potential use as a soil conditioner by successive experiments of absorption and release of two different aqueous nutrient solutions. Alginate-g-Acrylamide/Acrylic Acid hydrogels were obtained by electron beam irradiation using the linear accelerator ALID 7 at 5.5 MeV at the irradiation doses of 5 and 6 kGy. For this were prepared monomeric solutions that contained 1 and 2% sodium alginate, acrylamide and acrylic acid in ratios of 1:1 and 1.5:1, respectively, for the obtaining of materials with hybrid properties derived from natural and synthetic components. Physical, chemical, structural and morphological characteristics of the obtained hydrogels were investigated by specific analysis using swelling, diffusion and network studies and Fourier Transform Infrared Spectroscopy and Scanning Electron Microscopy. Four successive absorption and release experiments of some synthetic and natural aqueous solutions with nutrients were performed.
“…They are able to absorb water without dissolving, exceeding 1000- to 1500-fold their dry weight. 4 -11…”
Section: Introductionmentioning
confidence: 99%
“…They are able to absorb water without dissolving, exceeding 1000-to 1500-fold their dry weight. [4][5][6][7][8][9][10][11] Due to such significant properties, the SAPs are produced for different applications. For example, they are used in disposable baby diapers, 12,13 agriculture as soil amendments, 14,15 coal dewatering, 16 controlled release of drugs as carriers, 17,18 cosmetics 19 and absorbent pads, and wastewater treatment.…”
Superabsorbent polymers (SAPs) were synthesized by aqueous solution polymerization of carboxymethyl cellulose (CMC)/acrylic acid (AAc) and polyvinyl alcohol (PVA)/AAc blend using benzoyl peroxide as an initiator. SAPs were synthesized by a facile method under mild conditions. A comparative study was done between CMC/AAc as a biodegradable superabsorbent and PVA/AAc copolymer. The effects of cross-linking, reaction time, temperature, and initiator molar ratio on water absorbency were studied herein. The highest swelling capacity was obtained for CMC/AAc biodegradable superabsorbent composite. The water absorption capacity of SAPs increased with increases in benzoyl peroxide content, immersion time, and reaction temperature of polymerization. The gel fraction of SAPs decreased with increases in the amounts of N, N′-methylenebisacrylamide as a cross-linker. Fourier-transform infrared spectroscopy was used to examine the molecular interactions. The morphology and structure of superabsorbent composites were investigated by scanning electron microscopy.
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