Preparation and structure of rhodium phosphine compounds containing the [Rh2X7(PR3)2]- anion and their stereospecific reactions with phosphines to produce [Rh2X7(PR3)3]- species

Cotton, F. Albert; Kang, Seong Joo

doi:10.1021/ic00063a024

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Cited by 9 publications

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“…The structure of [P(C 6 H 5 ) 4 ][((H 3 C-CH 2 ) 3 P) 2 RhCl 4 ] can be found in: Cotton & Kang (1993) (CCDC:632517). Previous work on ((H 3 C) 3 P) 3 IrCl 3 can be found in: Merola et al (2013).…”

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confidence: 99%

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Trimethylphosphoniumtrans-tetrachloridobis(trimethylphosphane-κP)iridate(III)

2014

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The title compound, [HP(CH3)3][IrCl4{(H3C)3P}2], consists of a trimethylphosphonium cation and a tetrachloridobis(trimethylphosphane)iridate(III) anion. The anion has an octahedral arrangement of ligands, with the trimethylphosphane groups occupying trans positions. The IrIII atom sits on an inversion center with one P(CH3)3 ligand and two chloride ligands in the asymmetric unit. The trimethylphosphonium cation is disordered about a twofold rotation axis. The title compound is the first structurally characterized tetrachloridobis(phosphane)iridate complex.

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Section: Related Literaturementioning

confidence: 99%

“…The closest analog in the iridium family is a bis-phenyldimethylphosphane complex of iridium with two terminal chlorines and two chlorines bridging between iridium and palladium (Briant et al, 1981). The closest structure to the title iridium compound in the literature is the rhodium analog with triethylphosphane ligands (Cotton & Kang, 1993).…”

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confidence: 99%