Preparation and properties of UiO-66 based hybrid materials via surface initiated metal-free ATRP

Yang, Meimei; Wang, Yanhua; Li, Hongye; Bo, Peipei; Liu, Bo; Ge, Bo; Wang, Liping; Li, Guang

doi:10.1016/j.eurpolymj.2023.112612

Cited by 4 publications

(1 citation statement)

References 71 publications

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“…To obtain a more comprehensive understanding of the composition in UiO-66-Br 2 , PS/DVB, and UiO-66-Br 2 @PS/DVB, XPS analysis was conducted (Figure , Table ). As illustrated in Figure a, UiO-66-Br 2 mainly comprised C, O, Zr, and Br . The C 1s spectrum of UiO-66-Br 2 (Figure b) was resolved into four peaks at 284.80 285.56, 286.27, and 289.06 eV, representing C–C/CC, C–Br, C–O, and CO bonds, respectively.…”

Section: Resultsmentioning

confidence: 99%

Construction of Hierarchical Porous UiO-66-Br₂@PS/DVB-Packed Columns by High Internal Phase Emulsion Strategy for Enhanced Separation of CF₄/N₂ and SF₆/N₂

Miao,

Sui,

Weng

et al. 2024

ACS Appl. Mater. Interfaces

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Recovery and separation of anthropogenic emissions of electronic specialty gases (F-gases, such as CF 4 and SF 6 ) from the semiconductor sector are of critical importance. In this work, the hierarchical porous UiO-66-Br 2 @PS/DVB-packed column was constructed by a high internal phase emulsions strategy. UiO-66-Br 2 @PS/ DVB exhibits a superior selectivity of CF 4 /N 2 (2.67) and SF 6 /N 2 (3.34) predicted by the IAST due to the diffusion limitation in the micropore and the gas-framework affinity. Especially, UiO-66-Br 2 @ PS/DVB showed significant CF 4 and SF 6 retention and enabled the successful separation of CF 4 /N 2 and SF 6 /N 2 with a resolution of 2.37 and 8.89, respectively, when used as a packed column in gas chromatography. Compared with the Porapak Q column, the HETP of the UiO-66-Br 2 @PS/DVB-packed column decreased and showed good reproducibility. This research not only offers a convenient method for fabricating a hierarchical porous MOF-packed column but also showcases the prospective utilization of MOFs for the separation of the F-gas/N 2 mixture.

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Section: Resultsmentioning

confidence: 99%

Construction of Hierarchical Porous UiO-66-Br₂@PS/DVB-Packed Columns by High Internal Phase Emulsion Strategy for Enhanced Separation of CF₄/N₂ and SF₆/N₂

Miao,

Sui,

Weng

et al. 2024

ACS Appl. Mater. Interfaces

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Thermal and Mechanical Properties of Bio‐Based Polyamide 56/6 Filled with Talc

Zhang,

Yang,

Liu

et al. 2024

Macro Chemistry & Physics

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Polyamide composites with varying filler concentrations are prepared using the hot melt extrusion method, employing polyamide 56/6 (PA56/6) and modified talc as fillers. Initially, the thermal characteristics of PA56/6 composites (PA56/6‐talc) are examined through thermogravimetric analysis (TGA) and differential scanning calorimetry (DSC), encompassing parameters such as melting temperature, crystallinity, and decomposition temperature. The hydrophilicity and barrier properties of PA56/6‐talc are assessed using an optical contact angle meter, a water vapor transmission rate tester, and an oxygen transmission rate tester. Furthermore, the mechanical properties of PA56/6‐talc are also scrutinized. The results indicate that PA56/6 exhibits superior hydrophobic, barrier, and mechanical properties, thereby demonstrating its immense potential in garment fabrics and packaging materials.

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On the way to increase osseointegration potential: Sequential SI-ATRP as promising tool for PEEK-based implant nano-engineering

Ślusarczyk,

Flejszar,

Spilarewicz

et al. 2024

European Polymer Journal

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Preparation and properties of UiO-66 based hybrid materials via surface initiated metal-free ATRP

Cited by 4 publications

References 71 publications

Construction of Hierarchical Porous UiO-66-Br₂@PS/DVB-Packed Columns by High Internal Phase Emulsion Strategy for Enhanced Separation of CF₄/N₂ and SF₆/N₂

Construction of Hierarchical Porous UiO-66-Br₂@PS/DVB-Packed Columns by High Internal Phase Emulsion Strategy for Enhanced Separation of CF₄/N₂ and SF₆/N₂

Thermal and Mechanical Properties of Bio‐Based Polyamide 56/6 Filled with Talc

On the way to increase osseointegration potential: Sequential SI-ATRP as promising tool for PEEK-based implant nano-engineering

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Preparation and properties of UiO-66 based hybrid materials via surface initiated metal-free ATRP

Cited by 4 publications

References 71 publications

Construction of Hierarchical Porous UiO-66-Br2@PS/DVB-Packed Columns by High Internal Phase Emulsion Strategy for Enhanced Separation of CF4/N2 and SF6/N2

Construction of Hierarchical Porous UiO-66-Br2@PS/DVB-Packed Columns by High Internal Phase Emulsion Strategy for Enhanced Separation of CF4/N2 and SF6/N2

Thermal and Mechanical Properties of Bio‐Based Polyamide 56/6 Filled with Talc

On the way to increase osseointegration potential: Sequential SI-ATRP as promising tool for PEEK-based implant nano-engineering

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Product

Resources

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Construction of Hierarchical Porous UiO-66-Br₂@PS/DVB-Packed Columns by High Internal Phase Emulsion Strategy for Enhanced Separation of CF₄/N₂ and SF₆/N₂

Construction of Hierarchical Porous UiO-66-Br₂@PS/DVB-Packed Columns by High Internal Phase Emulsion Strategy for Enhanced Separation of CF₄/N₂ and SF₆/N₂