Abstract:To improve the heat absorbed and scattered properties of quartz fiber tile, porous phenolic resin impregnated quartz fiber tile composite for ablator and thermal insulator was prepared by impregnating the quartz fiber tile with ethanol solution of phenolic resin, and then drying and cured. The phenolic resin impregnated quartz fiber tile ablative composite is a new heat protection composite material with lower density, lower heat conductivity and low mass ablation. It can be used as the widespread thermal prot… Show more
“…In general, after the introduction of paraffin@Ba-TiO 3 nanofillers, the heat resistance properties of the composites have not been significantly affected, while the ablative property of the composites has increased due to the addition of inorganic filler. [25] XRD patterns of pure PI, pure BaTiO 3 and PI composites filled with various mass ratios of paraffin@BaTiO 3 nanoparticles are shown in Figure 4. Significantly, the pure PI presents a weak and broad peak centered at around 2θ = 19 , indicating the amorphous phase of the PI polymer chain.…”
Firstly, the BaTiO 3 nanoparticles were coated with a layer of paraffin, forming a core shell structure. Then, as-prepared paraffin@BaTiO 3 nanofillers were directly blended with polyimide (PI) prepolymer to fabricate paraffin@Ba-TiO 3 /PI composite films. The microstructure, thermal, and dielectric properties were investigated in detail. The surface-modified paraffin@BaTiO 3 nanoparticles exhibited a typical core shell structure with uniform and complete coverage. The char yield of the composite film with 10 wt% paraffin@BaTiO 3 increased from 56.40% to 70.73%. It is obvious that the paraffin@BaTiO 3 nanofillers have a positive effect on ablative performance of the composite film. Compared with pure PI, the ε r of paraffin@BaTiO 3 /PI composites with 40% mass fraction increased from 3.41 to 9.35 (1 kHz). The tanδ of paraffin@Ba-TiO 3 /PI composites was just 0.0065 (1 kHz) when the filler loading was 40 wt%.Temperature dependency of the permittivity of the composites reveals a zero-temperature-coefficient from 80 C to 180 C.
“…In general, after the introduction of paraffin@Ba-TiO 3 nanofillers, the heat resistance properties of the composites have not been significantly affected, while the ablative property of the composites has increased due to the addition of inorganic filler. [25] XRD patterns of pure PI, pure BaTiO 3 and PI composites filled with various mass ratios of paraffin@BaTiO 3 nanoparticles are shown in Figure 4. Significantly, the pure PI presents a weak and broad peak centered at around 2θ = 19 , indicating the amorphous phase of the PI polymer chain.…”
Firstly, the BaTiO 3 nanoparticles were coated with a layer of paraffin, forming a core shell structure. Then, as-prepared paraffin@BaTiO 3 nanofillers were directly blended with polyimide (PI) prepolymer to fabricate paraffin@Ba-TiO 3 /PI composite films. The microstructure, thermal, and dielectric properties were investigated in detail. The surface-modified paraffin@BaTiO 3 nanoparticles exhibited a typical core shell structure with uniform and complete coverage. The char yield of the composite film with 10 wt% paraffin@BaTiO 3 increased from 56.40% to 70.73%. It is obvious that the paraffin@BaTiO 3 nanofillers have a positive effect on ablative performance of the composite film. Compared with pure PI, the ε r of paraffin@BaTiO 3 /PI composites with 40% mass fraction increased from 3.41 to 9.35 (1 kHz). The tanδ of paraffin@Ba-TiO 3 /PI composites was just 0.0065 (1 kHz) when the filler loading was 40 wt%.Temperature dependency of the permittivity of the composites reveals a zero-temperature-coefficient from 80 C to 180 C.
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