“…It is currently accepted that visible emissions in ZnO stem from different intrinsic defects, such as oxygen vacancies (V O ), zinc vacancies (V Zn ), zinc interstitials (Zn i ), oxygen interstitials (O i ) and antisite defect (O Zn ). Recently, an unusual NV emission located around 400 nm has been observed in ZnO films [34][35][36], nanoparticles [37,38], nano/microfibers [39], whiskers [40] and nanorods [41]. However, the exact origin of the NV emission is not well understood and is still debatable.…”