Concrete is the most popular construction material in infrastructure projects due to its numerous natural advantages. Nevertheless, concrete constructions frequently suffer from low tensile strength and poor durability performance which are always urgent tasks to be solved. The concrete reinforced by various nanomaterials, especially graphene and its associated nanostructures (GANS), shows excellent chemical and physical properties for engineering applications. The influence of GANS on cement composites is a multiscale behavior from the nanoscale to the macroscale, which requires a number of efforts to reveal via numerical and experimental approaches. To meet this need, this study provides a comprehensive overview of the numerical modeling for GANS reinforced concrete in various scales. The background and importance of the topic are addressed in this study, along with the review of its methodologies, findings, and applications. Moreover, the study critically summarizes the performance of GANS reinforced concrete, including its mechanical behavior, transport phenomena, and failure mechanism. Additionally, the primary challenges and future prospects in the research field are also discussed. By presenting an extensive overview, this review offers valuable insights for researchers and practitioners interested in numerical simulation to advance concrete science and engineering.