Preparation and evaluation of zirconia microspheres as inorganic exchanger in adsorption of copper and nickel ions and as catalyst in hydrogen production from bioethanol
“…Srinivas et al [80] studied steam reforming of bio-ethanol over NiO/CeO 2 /ZrO 2 catalysts and found that the catalyst was stable for more than 500 h without deactivation. Bergamaschi et al [81] showed that Ni-Cu/ZrO 2 catalyst exhibits high activity for ethanol steam reforming with 100% conversion of ethanol and 60% selectivity to H 2 at 823 K.…”
“…Srinivas et al [80] studied steam reforming of bio-ethanol over NiO/CeO 2 /ZrO 2 catalysts and found that the catalyst was stable for more than 500 h without deactivation. Bergamaschi et al [81] showed that Ni-Cu/ZrO 2 catalyst exhibits high activity for ethanol steam reforming with 100% conversion of ethanol and 60% selectivity to H 2 at 823 K.…”
“…It is easier and cheaper to prepare than the organic resins. However, hydrous zirconium oxide is not amenable to efficient regeneration [22][23][24].…”
“…It was concluded that high temperature (550°C), higher water/ethanol molar ratio (3:1) promote on Ni/Cu/ZrO 2 high hydrogen yield (60 %) (Bergamaschi et al, 2005).…”
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