Preparation and characterization of sucrose-based microporous carbons for increasing hydrogen storage

Choi, Yong‐Ki; Park, Soo‐Jin

doi:10.1016/j.jiec.2015.02.012

Cited by 22 publications

(13 citation statements)

References 33 publications

(36 reference statements)

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“…Carbon-based nanomaterials have received considerable attention as potential hydrogen storage materials because of their low costs, low weights, high surface areas, high chemical stabilities, and wide diversities of bulk and pore structures [83][84][85][86][87][88][89]. In particular, many industrial applications are expected because of their moisture-resistant properties.…”

Section: Carbonaceous Materials For Hydrogen Storagementioning

confidence: 99%

Recent Progress Using Solid-State Materials for Hydrogen Storage: A Short Review

Lee

Kim

et al. 2022

Processes

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With the rapid growth in demand for effective and renewable energy, the hydrogen era has begun. To meet commercial requirements, efficient hydrogen storage techniques are required. So far, four techniques have been suggested for hydrogen storage: compressed storage, hydrogen liquefaction, chemical absorption, and physical adsorption. Currently, high-pressure compressed tanks are used in the industry; however, certain limitations such as high costs, safety concerns, undesirable amounts of occupied space, and low storage capacities are still challenges. Physical hydrogen adsorption is one of the most promising techniques; it uses porous adsorbents, which have material benefits such as low costs, high storage densities, and fast charging–discharging kinetics. During adsorption on material surfaces, hydrogen molecules weakly adsorb at the surface of adsorbents via long-range dispersion forces. The largest challenge in the hydrogen era is the development of progressive materials for efficient hydrogen storage. In designing efficient adsorbents, understanding interfacial interactions between hydrogen molecules and porous material surfaces is important. In this review, we briefly summarize a hydrogen storage technique based on US DOE classifications and examine hydrogen storage targets for feasible commercialization. We also address recent trends in the development of hydrogen storage materials. Lastly, we propose spillover mechanisms for efficient hydrogen storage using solid-state adsorbents.

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Section: Carbonaceous Materials For Hydrogen Storagementioning

confidence: 99%

Recent Progress Using Solid-State Materials for Hydrogen Storage: A Short Review

Lee

Kim

et al. 2022

Processes

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“…With an exceptionally large surface area, a microporous nature and the possibility of an economic and scalable production, ACs are excellent candidates in efficient hydrogen storage systems [58,[87][88][89][90][91][92][93][94][95][96][97][98][99][100][101][102][103]. One of the most important advantages of ACs is that they can be produced from a wide variety of low-cost and renewable raw materials, such as agricultural waste or lignocellulosic materials in general, which is an important advantage compared to other carbon materials [104].…”

Section: Activated Carbonsmentioning

confidence: 99%

Characterization of Carbon Materials for Hydrogen Storage and Compression

Sdanghi

Canevesi

Celzard

et al. 2020

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Carbon materials have proven to be a suitable choice for hydrogen storage and, recently, for hydrogen compression. Their developed textural properties, such as large surface area and high microporosity, are essential features for hydrogen adsorption. In this work, we first review recent advances in the physisorption characterization of nanoporous carbon materials. Among them, approaches based on the density functional theory are considered now standard methods for obtaining a reliable assessment of the pore size distribution (PSD) over the whole range from narrow micropores to mesopores. Both a high surface area and ultramicropores (pore width < 0.7 nm) are needed to achieve significant hydrogen adsorption at pressures below 1 MPa and 77 K. However, due to the wide PSD typical of activated carbons, it follows from an extensive literature review that pressures above 3 MP are needed to reach maximum excess uptakes in the range of ca. 7 wt.%. Finally, we present the adsorption–desorption compression technology, allowing hydrogen to be compressed at 70 MPa by cooling/heating cycles between 77 and 298 K, and being an alternative to mechanical compressors. The cyclic, thermally driven hydrogen compression might open a new scenario within the vast field of hydrogen applications.

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“…The development of the porosity is a consequence of carbon oxidation (etching) due to the redox reaction between potassium hydroxide and carbon with the formation of carbonates, release of volatiles (H2, COx) and intercalation of K, according to the following equations (Choi and Park, 2015;Wang et al, 2009):…”

Section: Hydrogen Storagementioning

confidence: 99%

Gas storage

Peredo-Mancilla

Ghouma

Hort

et al. 2019

Char and Carbon Materials Derived From Biomass

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The continuous increase of energy demands based on fossil fuels in the last years have lead to an increase of greenhouse gases (GHG) emission which strongly contribute to global warming. The main strategies to limit this phenomenon are related to the efficient capture of these gases and to the development of renewable energies sources with limited environmental impact. Particularly, carbon dioxide (CO2) and methane (CH4) are the main constituents of greenhouse gases while hydrogen (H2) is considered an alternative clean energy source to fossil fuels. Therefore, tremendous research to store these gases has been reported by several approaches and among them the physisorption on activated carbons (AC) have received significant attention. Their abundance, low cost and tunable porous structure and chemical functionalities with an existing wide range of precursors that includes bio-wastes make them ideal candidates for gas applications. This chapter presents the recent developments on CH4, CO2 and H2 storage by activated carbons with focus on biomass as precursor materials. An analysis of the main carbon properties affecting the AC's adsorption capacity (i.e. specific surface area, pore size and surface chemistry) is discussed in detail herein.

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Preparation and characterization of sucrose-based microporous carbons for increasing hydrogen storage

Cited by 22 publications

References 33 publications

Recent Progress Using Solid-State Materials for Hydrogen Storage: A Short Review

Recent Progress Using Solid-State Materials for Hydrogen Storage: A Short Review

Characterization of Carbon Materials for Hydrogen Storage and Compression

Gas storage

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