Preparation and characterization of rhenium (I) tricarbonyl dithiocarbamate compounds; Re(CO)3(S2CNMe2)(L)

Herrick, Richard S.; Ziegler, Christopher J.; Sripothongnak, Saovalak; Barone, Natalie; Costa, Roshinee; Cupelo, William; Gambella, Americo

doi:10.1016/j.jorganchem.2009.08.008

Cited by 25 publications

(12 citation statements)

References 38 publications

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“…compared to the other structural analogues. Further, these trends are clearly reflected in the blue shift of the CO vibrational band for L = C-type donor ligands, with an average Á = 180 cm À1 , compared with those for N-and P-type donors (Herrick et al, 2009). In the present study, (CO) for (I) was observed at 1883 cm À1 .…”

Section: Database Surveysupporting

confidence: 58%

“…A series of eight closely related structural analogues with the formula [Re(CO) 3 (S 2 CNMe 2 )L], where L = ammonia (NH 3 ) (1), pyridine (py) (2), imidazole (Im) (3), pyrazole (pz) (4), triphenylphosphine (PPh 3 ) (5), 1,3,5-triaza-7-phosphaadamantane (PTA) (6), t-butyl isocyanide (tBuNC) (7) and cyclohexyl isocyanide (CyNC) (8) have been reported previously (Herrick et al, 2009). The bond lengths about the Re I atom in 1-8 and (I) are collated in Table 3; the numbering schemes correspond to that shown in Fig.…”

Section: Database Surveymentioning

confidence: 99%

“…The molecular packing in (I): (a) supramolecular chain sustained by methyl-C-HÁ Á ÁO(carbonyl) interactions shown as orange dashed lines, (b) view of the supramolecular layers in the ab plane with nonparticipating H atoms removed and (c) a view of the unit-cell contents in projection down the a axis. research communications Table 3 Selected bonding parameters (Å ) for (I) and literature analogues [Re(CO) 3 (S 2 CNMe 2 )L].. L = ammonia (NH 3 ) (1), pyridine (py) (2), imidazole (Im) (3), pyrazole (pz) (4), triphenylphosphine (PPh 3 ) (5), 1,3,5-triaza-7-phosphaadamantane (PTA) (6), tbutyl isocyanide (tBuNC) (7) and cyclohexyl isocyanide (CyNC) (8) (Herrick et al, 2009). compared to the other structural analogues.…”

Section: Database Surveymentioning

confidence: 99%

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fac-Acetonitriletricarbonyl(dimethylcarbamodithioato-κ²S,S′)rhenium(I): crystal structure and Hirshfeld surface analysis

et al. 2017

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Section: Database Surveysupporting

confidence: 58%

Section: Database Surveymentioning

confidence: 99%

Section: Database Surveymentioning

confidence: 99%

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fac-Acetonitriletricarbonyl(dimethylcarbamodithioato-κ²S,S′)rhenium(I): crystal structure and Hirshfeld surface analysis

et al. 2017

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“…To the best of our knowledge, complex 1 constitutes the first Mn‐PTA complex characterised by single crystal structure analysis where the phosphorus atom coordinates to the manganese central atom. The same coordination environment as in complex 1 is also found in the rhenium diethyldithiocarbamato complex fac ‐[Re(S 2 CNEt 2 )(PTA)(CO) 3 ] which was prepared in an analogous manner 8. However, the two compounds are not isostructural.…”

Section: Resultsmentioning

confidence: 56%

Synthesis, Structures, and CO Releasing Properties of two Tricarbonyl Manganese(I) Complexes

Mohr

Niesel

Schatzschneider

et al. 2011

Zeitschrift anorg allge chemie

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[MnBr(CO)₅] reacts with one equivalent each of 1, 3, 5-triaza-7-phosphaadamantane (PTA) and sodium diethyldithiocarbamate to afford the yellow Mn^I complex fac-[Mn(S₂CNEt₂)(PTA)(CO)₃]. Similarly, the same Mn^I precursor reacts with the sodium salt ofL-histidine to give the tricarbonyl manganese(I) complex fac-[Mn(his)(CO)₃] in good yield as a yellow solid. Both compounds were spectroscopically and structurally characterised. The histidinato complex is soluble in water and its aqueous solutions are stable for more than 24 h. The CO releasing properties of the histidinato complex were studied with the myoglobin assay and establish this compound as a novel PhotoCORM, which liberates one of the three carbonyl ligands upon irradiation

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“…These values differ significantly between the two compounds and are most likely caused by the bridging ligand in (1) that is sterically prevented from forming a third bridge. The rheniumcarbonyl and rhenium-sulfur bond lengths of (1) and (2) are in normal ranges (Alberto & Schubiger, 1989;Alberto et al, 1996Schutte et al, 2012;Brink et al, 2014;Makris et al, 2012;Nú ñ ez-Montenegro et al, 2014;Herrick et al, 2009;Vanitha et al, 2010).…”

Section: X-ray Crystallographymentioning

confidence: 99%

Synthesis of Re^Itricarbonyl complexes with various sulfur- and oxygen-donating ligands: crystal structures of two Re^Idinuclear structures bridged by S atoms

et al. 2018

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The synthesis and characterization of two dinuclear complexes, namely fachexacarbonyl-1 3 C,2 3 C-(pyridine-1N)[-2,2 0 -sulfanediyldi(ethanethiolato)-1 2 S 1 ,S 3 :2 3 S 1 ,S 2 ,S 3 ]dirhenium(I), [Re 2 (C 4 H 8 S 3 )(C 5 H 5 N)(CO) 6 ], (1), and tetraethylammonium fac-tris(-2-methoxybenzenethiolato-2 S:S)bis[tricarbonylrhenium(I)], (C 8 H 20 N)[Re 2 (C 7 H 7 OS) 3 (CO) 6 ], (2), together with two mononuclear complexes, namely (2,2 0 -bithiophene-5-carboxylic acid-2 S,S 0 )bromidotricarbonylrhenium(I), (3), and bromidotricarbonyl(methyl benzo[b]thiophene-2-carboxylate-2 O,S)rhenium(I), (4), are reported. Crystals of (1) and (2) were characterized by X-ray diffraction. The crystal structure of (1) revealed two Re-S-Re bridges. The thioether S atom only bonds to one of the Re I metal centres, while the geometry of the second Re I metal centre is completed by a pyridine ligand. The structure of (2) is characterized by three S-atom bridges and an ReÁ Á ÁRe nonbonding distance of 3.4879 (5) Å , which is shorter than the distance found for (1) [3.7996 (6)/3.7963 (6) Å ], but still clearly a nonbonding distance. Complex (1) is stabilized by six intermolecular hydrogen-bond interactions and an OÁ Á ÁO interaction, while (2) is stabilized by two intermolecular hydrogen-bond interactions and two OÁ Á Á interactions.

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Preparation and characterization of rhenium (I) tricarbonyl dithiocarbamate compounds; Re(CO)3(S2CNMe2)(L)

Cited by 25 publications

References 38 publications

fac-Acetonitriletricarbonyl(dimethylcarbamodithioato-κ²S,S′)rhenium(I): crystal structure and Hirshfeld surface analysis

fac-Acetonitriletricarbonyl(dimethylcarbamodithioato-κ²S,S′)rhenium(I): crystal structure and Hirshfeld surface analysis

Synthesis, Structures, and CO Releasing Properties of two Tricarbonyl Manganese(I) Complexes

Synthesis of Re^Itricarbonyl complexes with various sulfur- and oxygen-donating ligands: crystal structures of two Re^Idinuclear structures bridged by S atoms

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Preparation and characterization of rhenium (I) tricarbonyl dithiocarbamate compounds; Re(CO)3(S2CNMe2)(L)

Cited by 25 publications

References 38 publications

fac-Acetonitriletricarbonyl(dimethylcarbamodithioato-κ2S,S′)rhenium(I): crystal structure and Hirshfeld surface analysis

fac-Acetonitriletricarbonyl(dimethylcarbamodithioato-κ2S,S′)rhenium(I): crystal structure and Hirshfeld surface analysis

Synthesis, Structures, and CO Releasing Properties of two Tricarbonyl Manganese(I) Complexes

Synthesis of ReItricarbonyl complexes with various sulfur- and oxygen-donating ligands: crystal structures of two ReIdinuclear structures bridged by S atoms

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fac-Acetonitriletricarbonyl(dimethylcarbamodithioato-κ²S,S′)rhenium(I): crystal structure and Hirshfeld surface analysis

fac-Acetonitriletricarbonyl(dimethylcarbamodithioato-κ²S,S′)rhenium(I): crystal structure and Hirshfeld surface analysis

Synthesis of Re^Itricarbonyl complexes with various sulfur- and oxygen-donating ligands: crystal structures of two Re^Idinuclear structures bridged by S atoms