In this paper, structural and optical properties of undoped and sliver doped titanium dioxide film have been studied. By using Sol-gel method undoped and sliver doped titanium dioxide (TiO 2) thin film synthesis on FTO glass substrate. Sliver has been doped 3%,7%, concentration in titanium dioxide (TiO 2) .Different properties such as, crystal structure, phase identification, thickness, band gap, transmission and absorption spectrum have been studied using X-ray diffraction (XRD), Raman spectroscopy, UV/Vis spectrophotometry. The results showed that undoped and Ag doped TiO 2 thin film annealed at 450 o c had anatase phases and there is no Ag peaks in X-ray diffraction.