Preparation and characterization of new chiral ferrocenyl selenides

Białek, Dariusz; Kowalski, Konrad; Ścianowski, Jacek; Rafiński, Zbigniew; Wojtczak, Andrzej

doi:10.1016/j.jorganchem.2012.03.032

Cited by 4 publications

(1 citation statement)

References 59 publications

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“…In 2012, Wojtczak explained how to synthesize chiral ferrocenyl selenides (Scheme 30). [48] The researchers did this by mixing the 1,1′‐dilithioferrocene‐TMEDA adduct with either (+)‐dineomenthyl diselenide or (−)‐bis(cis‐myrtanyl) diselenide. Based on what we know so far, this is the first record of chiral ferrocene selenides of this kind.…”

Section: Synthesis Of Chiral Organoselenium Compoundsmentioning

confidence: 99%

Recent Progress in Synthesis and Application of Chiral Organoselenium Compounds

Lai,

Liang,

Zeng

2024

Chemistry A European J

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Chiral organoselenium compounds have shown an important role as intermediates in many areas, such as drug discovery, organic catalysis, and nanomaterials. A lot of different methods have been developed to synthesize chiral compounds which contain selenium, because they have interesting properties and can be used in real life. Over the last few decades, a lot of progress has been made in making chiral organoselenium compounds synthetically. This work gives an overview of the progress made in creating new ways to synthesize chiral organoselenium compounds by categorizing them into groups based on the reactions they undergo. In addition, the use of chiral organoselenium compounds is also discussed.

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Section: Synthesis Of Chiral Organoselenium Compoundsmentioning

confidence: 99%

Recent Progress in Synthesis and Application of Chiral Organoselenium Compounds

Lai,

Liang,

Zeng

2024

Chemistry A European J

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Recent Advances in Transition‐Metal‐Catalyzed C−H Functionalization of Ferrocene Amides

Mou

Zhao

Sun

2022

Chemistry An Asian Journal

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During the past decades, in synthetic organic chemistry, directing-group-assisted CÀ H functionalization is found to be a key tool for the expedient and site-selective construction of CÀ C and hybrid bonds. Among CÀ H functionalization of ferrocene derivatives, the directed group strategy is undoubtedly the most commonly used method. Compared to the other directing groups, ferrocene amides can be synthesized easily and are now recognized as one of the most efficient tools for the selective functionalization of certain positions because its metal centre permits fine, tuneable and reversible coordination. The family of amide directing groups mainly comprises monodentate and bidentate directing groups, which are categorized on the basis of coordination sites. In this review, various CÀ H bond functionalization reactions of ferrocene using amide directing groups are broadly discussed.

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Asymmetric Synthesis with Organoselenium Compounds – The Past Twelve Years

Stadel,

Back

2024

Chemistry A European J

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The discovery and synthetic applications of novel organoselenium compounds and their reactions proceeded rapidly during the past fifty years and such processes are now carried out routinely in many laboratories. At the same time, the growing demand for new enantioselective processes provided new challenges. The convergence of selenium chemistry and asymmetric synthesis led to key developments in the 1970s, although the majority of early work was based on stoichiometric processes. More recently, greater emphasis has been placed on greener catalytic variations, along with the discovery of novel reactions and a deeper understanding of their mechanisms. The present review covers the literature in this field from 2010 to early 2023 and encompasses asymmetric reactions mediated by chiral selenium‐based reagents, auxiliaries and, especially, catalysts. Protocols based on achiral selenium compounds in conjunction with other species of chiral catalysts, as well as reactions that are controlled by chiral substrates, are also included.

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Preparation and characterization of new chiral ferrocenyl selenides

Cited by 4 publications

References 59 publications

Recent Progress in Synthesis and Application of Chiral Organoselenium Compounds

Recent Progress in Synthesis and Application of Chiral Organoselenium Compounds

Recent Advances in Transition‐Metal‐Catalyzed C−H Functionalization of Ferrocene Amides

Asymmetric Synthesis with Organoselenium Compounds – The Past Twelve Years

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