2019
DOI: 10.1016/j.carbpol.2019.01.093
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Preparation and characterization of cellulose nanofibrils from coconut coir fibers and their reinforcements in biodegradable composite films

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Cited by 104 publications
(39 citation statements)
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“…The possible explanation for this evident drop of T onset can be suggested as follows. Firstly, high crystallinity cannot ensure enhanced thermal stability especially when the sample size belongs to nanoscale, which is in good agreement with our early findings (Wu et al, 2019). Secondly, heat-labile sulfate esters formed on the surface of RW-CNC not only interrupt the linkages of intermolecular hydrogen bonds among RW-CNCs, but also turn out to be more vulnerable during TGA (Tuerxun et al, 2019).…”
Section: Thermal Stability Of Different Fiber-based Samplessupporting
confidence: 84%
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“…The possible explanation for this evident drop of T onset can be suggested as follows. Firstly, high crystallinity cannot ensure enhanced thermal stability especially when the sample size belongs to nanoscale, which is in good agreement with our early findings (Wu et al, 2019). Secondly, heat-labile sulfate esters formed on the surface of RW-CNC not only interrupt the linkages of intermolecular hydrogen bonds among RW-CNCs, but also turn out to be more vulnerable during TGA (Tuerxun et al, 2019).…”
Section: Thermal Stability Of Different Fiber-based Samplessupporting
confidence: 84%
“…To date, numerous species of lignocellulosic wastes (e.g., bagasse, cornstalk, coconut husk, etc.) have been attempted for isolation of cellulose (Ditzel et al, 2017;Tuerxun et al, 2019;Wu et al, 2019;Ejaz et al, 2020;Kian et al, 2020; and meanwhile the obtained cellulose could be further processed for high-value utilization.…”
Section: Introductionmentioning
confidence: 99%
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“…33 In the TGA curves presented by weight (%) and solid line, the apparent weight loss of the BLCNF-f lm began at 234 C, while the other three lms began at a higher temperature of 257 C under nitrogen atmosphere. From the DTG curves shown by the dotted line, it can be seen that all H 2 SO 4 -CNF-f, SCCNF-f and SCCNF-f lms exhibited a prominent pyrolysis process with mainly single degradation and the accompanying weight loss mostly occurred at 257-375 C. Whereas, the signicant pyrolysis of the BLCNF-f lm took place in a relatively low temperature range of 242-359 C, and was accompanied by an obvious shoulder around 242-296 C. The shoulder peak might be triggered by the degradation of hemicellulose since its lower thermal stability compared with lignin and cellulose, 34 and the BLCNF-f was speculated to have the highest hemicellulose content in all samples from the composition results in Table 1. In all curves, the weight loss in the temperature range of about 300-375 C should be attributed to the decomposition of lignin and cellulose.…”
Section: Thermal Stability Of Cnf Lmsmentioning
confidence: 99%
“…Hence, some authors have driven the further development of mechanical isolation and evaluated the efficiency and effectiveness of preparing nanocellulose using non-conventional mechanical treatments such as high-speed blending, steam explosion, 102 ball milling and highintensity ultrasonication. 97,[103][104][105][106][107][108][109][110] Khawas and Deka have revealed that the introduction of high-intensity ultrasonication assisted the reduction of CNF size and diameter, which enhanced the thermal stability with increased degradation temperature from 260.81 o C to 295.33 o C when coupled with ultrasonication power of 1 kW. 105 The effectiveness of this approach has been further investigated by Zhang et al and Yazdanbakhsh et al who have successfully optimized combination of chemical-mechanical process.…”
Section: Mechanical Treatmentmentioning
confidence: 99%