Preparation, Adsorption Properties, and Catalytic Activity of 3D Porous Metal–Organic Frameworks Composed of Cubic Building Blocks and Alkali‐Metal Ions

Synthesis, characterization and crystal structure of a 2D Cd(II) complex with a 4,4'‐diazenediyldiphthalic acid ligand

“…The rational design and syntheses of novel coordination polymers have achieved considerable progress in the field of supramolecular chemistry and crystal engineering, owing to their potential applications as gas storage [1], sensor technology [2], separation processes [3], ion exchange [4], luminescene [5], magnetism [6], and catalysis [7], as well as due to their intriguing variety of architectures and topologies. Crystal engineering of solid-state supramolecular entities such as coordination polymers has provided a nice bit of successful examples for the rational assembly of target materials, which are normally realized by deliberate design of the ligands with adjustable connectivity and/or judicious selection of metal ions with specific coordination tendency [8].…”

MoS2–Ni Nanocomposites as Catalysts for Hydrodesulfurization of Thiophene and Thiophene Derivatives

“…The substrate vapors were carried at a constant partial pressure of 100 mbar (1 mbar = 100 Pa) by a flow of hydrogen (20 mL min -1 ). The gas mixture emerging from the microreactor was analyzed through an online mass spectrometer (MMC-200, Ulvac) and a gas chromatograph (MT-221, GL Science) [19]. …”

Recyclable Cu-MOF-74 Catalyst for Ligand-Free O-Arylation Reaction of 4-Nitrobenzaldehyde and Phenol

“…MOF materials are porous crystalline solids with surface areas surpassing activated carbons and zeolites, composed by metal nodes connected by organic linkers through strong chemical bonds [14]. Although MOF materials have been originally used for gas separation and storage, their potential as active and selective catalysts in a wide range of chemical 2 of 13 reactions are being lately demonstrated [15][16][17][18][19]. Phan and co-workers have paid attention on ligand-free copper-catalyzed coupling reactions of phenols with aryl iodines or nitroarenes [20] using MOF-199 and Cu2(BDC)2(DABCO) (BDC = 1,4-bencene dicarboxylate and DABCO = 1,4-diazabicyclo[2,2,2]octane), respectively.…”