We measured the Raman spectra of Mizuho and Nansen ice
recovered from Antarctica, and Dye-3 ice recovered
from Greenland, to observe the translational lattice vibrations in
polar ice. Since we investigated the effect
of the aging on the ice and the ice temperature on the spectra, we
chose to study the ice from three different
sites. The ages of the ice Ih range from 4.6 to 100 kyr. The
ice temperatures at the depth it was located
range from 231 to 260 K. The results were compared with the
measurements taken of the Vostok ice by
Fukazawa et al. We found that the relative intensity of the peak
at 300 cm-1 increased as the temperature
at
which the ice was kept for a long period increased from 214 to 237 K.
Since this peak is assigned to a
translational lattice vibration traveling along the hydrogen-bonding
network, we conclude that the structure
of the network in the polar ice varies with time at a very slow rate to
attain an equilibrium state that has
never been found on the laboratory time scale.