Glass fibers with a diameter of Ĭ100 mm are drawn by just pulling up melts of 40BaOெ20TiO 2 ெ40SiO 2 glass, and transparent crystallized glass fibers consisting of nonlinear optical fresnoite Ba 2 TiSi 2 O 8 nanocrystals particle size: Ĭ100-200 nm are fabricated by crystallization of glass fibers. Precursor glass fibers and nanocrystallized glass fibers are etched chemically using a meniscus method, in which an etching solution of 0.1 wt!-HFhexane is used. Glass fibers with sharpened tips e.g., the taper length is ĬL 200 mm and the tip angle is Ĭu 23? are obtained. It is found that etched nanocrystallized glass fibers also have sharpened tips L 50 mm, u 80? . Compared with precursor glass fibers, nanocrystallized glass fibers show a high resistance against chemical etching in a 0.1 wt!HF solution. Although sharpened tips in nanocrystallized glass fibers do not have nanoscaled apertures, the present study suggests that nanocrystallized glass fibers showing second harmonic generations would have a potential for fiber-type light control optical devices.