TiO2−xNy/Ag‐PbMoO4 composite were synthesized by sonochemical method. The results revealed that the band‐gap energy absorption edge of TiO2−xNy/Ag‐PbMoO4 composite was shifted to a longer wavelength as compared to TiO2, TiO2−xNy, PbMoO4, and Ag‐PbMoO4. The TiO2−xNy/Ag‐PbMoO4 composite showed the enhanced photocatalytic activity for degradation of indigo carmine dye (ICD) under simulated solar light irradiation. The TiO2−xNy/Ag‐PbMoO4 composite exhibited the highest percentage (95.4%) of degradation of ICD and the highest reaction rate constant (0.0244 min−1) in 2 h. The results suggested that a good combination of Ag and TiO2−xNy nanoparticles has great influence on the photocatalytic behavior of PbMoO4.