Prediction of Surface Segregation of Fluorinated Additives from Measurement of Wettability Properties of Polymer-Based Blends
Rachel Le Brouster,
Julien Giboz,
Ali Nourdine
et al.
Abstract:The aim of this work is to describe the segregation phenomenon
of random perfluorinated copolymers toward the surface of a polystyrene
(PS) matrix. Three random perfluorinated copolymers, named POISE-a
(Polymer prOcessing Interface StabilizEr), synthesized with different
amounts of chemically bound fluorine, were mixed with a commercial
PS matrix by a solvent casting process. Their effect on the wettability
properties of PS as a function of their concentration was measured
first under static conditions with di… Show more
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