Prediction of phase behavior, Henry's constants, and infinite dilution partial molar volumes for carbon dioxide and carbon monoxide in n-paraffins

Bader, M.S.H.; Gasem, Khaled A. M.

doi:10.1016/s0896-8446(96)90056-x

Cited by 7 publications

(2 citation statements)

References 59 publications

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“…Generalized correlations for C,, and D,, are given by Equations (29) and (30). These parameters (C12 and D,,) are dependent on the dissimilarity in the molecular species in the system; the more dissimilarity in the molecular species, the greater the need for such parameters and the larger the values observed (Bader, 1993;Bader and Gasem, 1996b).…”

Section: T P and 0)mentioning

confidence: 99%

Modeling infinite dilution activity coefficients of organic‐aqueous systems using a modified regular solution equation and cubic equations‐of‐state

Bader

Gasem

1998

Can J Chem Eng

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Expressions derived from the regular solution equation and the generalized cubic equations-of-state (EOS) were employed to model the infinite dilute activity coefficient (y-) of organic-aqueous systems. A database of 1 19 organic species in aqueous systems, divided into six classes, was gathered for models evaluations. The use of the molar density, the first order molecular connectivity, and the dipole moment appear to be adequate correlating variables for describing the structural dependence of the residual part in the modified regular solution equation (MRS). The Soave-RedlichKwong (SRK) and Peng-Robinson (PR) were specified and employed in the generalized cubic EOS form. The excess activity coefficient concept was used in the SRK and PR EOS models to account for the deficiency of EOS in dealing with highly non-ideal or polar systems. The abilities of two existing correlation models along with two modified versions of the UNIFAC model were also assessed. The proposed models provide creditable equations for correlating y-of organic-aqueous systems. tringent environmental regulations in the fields of water S reuse and wastewater management have increased the industrial significance of predictive models for the phase behavior of organic species in aqueous systems. The fate of trace organic species in the environment is typically described in terms of thermodynamic properties such as Henry's constants, octanol-water partition coefficients, and aqueous solubilities. Such properties are needed, for instance, to predict: (1) water-air phase exchanges (Henry's constant), (2) the ability of the organic solute to bioaccumulate and its ability to sorb in soils and sediments (octanolwater partition coefficient), and (3) trace water-organic phase distribution (mutual solubility). When experimental measurements for Henry's constant, octanol-water partition coefficient, and mutual solubility are not available, they can be calculated from y-. However, all experimental methods employed to measure y" suffer from some limitations (Tiegs et al., 1986;Bader, 1993; Bader and Gasem, 1996a). The current experimental methods are inapplicable for a large number of organic-aqueous systems; systems that are challenging to characterize. Thus, generalized models for predicting ym of organic-aqueous systems based on pure component properties and limited binary mixture data are often needed.*Author to whom correspondence may be addressed. E-mail address: This work is devoted to the modeling of yw of organicaqueous systems. The objectives of this work are to: (1) modify the regular solution equation; (2) apply and amend the generalized form of cubic EOS (SRK and PR); and (3) test the abilities of two existing correlation models as well as two modified versions of the UNIFAC model. Literature reviewTwo different types of models are used to correlate andor predict yw. These models are either based on component properties or group contribution methods. COMPONENT-BASED MODELSThe regular solution theory (Scatchard, 193 1;Hildebrand and Wood, 1933...

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Section: T P and 0)mentioning

confidence: 99%

Modeling infinite dilution activity coefficients of organic‐aqueous systems using a modified regular solution equation and cubic equations‐of‐state

Bader

Gasem

1998

Can J Chem Eng

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“…Было обнаружено, что использование кубических уравнений состояния позволяет рассчитать константу Генри для бинарных систем растворитель-растворенное вещество при отсутствии химических взаимодействий между ними [8]. Так в работе Хольдербаума и Гмелинга [9] при помощи моделей расчета активностей, основанных на уравнениях состояния, было рассчитано равновесие растворов кислорода, азота, углекислого газа, монооксида углерода, сероводорода, метана, этана, пропана и бутана в кетонах, спиртах, н-алканах и воде.…”

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Calculation of Thermodinamic Parameters of Hydrogen Absorption in Different Solvents

Степачёва¹,

Markova²,

Монжаренко³

et al. 2020

Вестник Тверского Государственного Университета. Серия: Химия

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В данной работе были проведены исследования растворимости водорода в различных растворителях. Было изучено влияние условий (температуры и давления, а также скорости перемешивания) на растворимость водорода в воде, пропаноле-2, н-гексане, толуоле и н-додекане. Было исследование влияние наличия катализатора на растворимость водорода. Расчет термодинамических параметров абсорбции водорода проводился с использованием уравнения состояния Соаве-Редлиха-Квонга. In the current work, the solubility of hydrogen in different solvents was studied. The influence of process conditions (temperature, pressure and stirring rate) on the hydrogen absorption in water, propanol-2, n-hexane, toluene and n-dodecane was estimated. The effect of the catalyst presence on the gas absorption was also investigated. The calculation of thermodynamic parameters of gas solubility in different solvent was done according to the Soave-Redlich-Kwong equation of state.

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Prediction of the infinite-dilution partial molar volumes of organic solutes in supercritical carbon dioxide using the Kirkwood-Buff fluctuation integral with the hard sphere expansion (HSE) theory

Kwon

Lee

2005

Korean J. Chem. Eng.

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Prediction of phase behavior, Henry's constants, and infinite dilution partial molar volumes for carbon dioxide and carbon monoxide in n-paraffins

Cited by 7 publications

References 59 publications

Modeling infinite dilution activity coefficients of organic‐aqueous systems using a modified regular solution equation and cubic equations‐of‐state

Modeling infinite dilution activity coefficients of organic‐aqueous systems using a modified regular solution equation and cubic equations‐of‐state

Calculation of Thermodinamic Parameters of Hydrogen Absorption in Different Solvents

Prediction of the infinite-dilution partial molar volumes of organic solutes in supercritical carbon dioxide using the Kirkwood-Buff fluctuation integral with the hard sphere expansion (HSE) theory

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