Prediction of neutral noble gas compounds LiNgF (Ng = Kr, Xe and Rn)

Long‐bonding and effects of carbon hybridization on the bonding of MNgC compounds (M = Cu, Ag, Au)

“…During this time, several key works contributed to the development of noble gas chemistry, including Pauling's theoretical prediction of the existence of the noble gas fluorides in 1933 [1], Neil Bartlett's successful synthesis of Xe + [PtF 6 ] − in 1962 [2], and Räsänen's synthesis of HArF using HF photocatalysis in Ng matrix in 2001 [3]. In recent years, many compounds formed by noble gases and various chemical elements have been synthesized experimentally and/or predicted theoretically [3–37]. It seems that noble gases can bond with every element in the periodic table and plug into any bond to form insertion compounds.…”

“…It seems that noble gases can bond with every element in the periodic table and plug into any bond to form insertion compounds. Many typical noble gas insertional compounds were reported, including HNgCCF(Ng = ArXe) [4], HXeOBr [5], HNgCCO + (Ng = HeXe) [6], HNgMX 3 (Ng = ArRn, M = BeCa, X = FBr) [7], HNgMO(M = B, Al) [8], LiNgF [9], FNgBS(Ng = Ar, Kr and Xe) [10], BNg 3 F 3 (Ng = ArXe) [11], FNgBNR(Ng = Ar, Kr, Xe, R = H, CH 3 , CCH, F, OH) [12], FNgCC − (Ng = HeRn) [13], F 4 XeOsF 4 [14] and so on.…”