2020
DOI: 10.1016/j.supflu.2020.104909
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Predicting the solubilities of metal acetylacetonates in supercritical CO2: Thermodynamic approach using PC-SAFT

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Cited by 18 publications
(2 citation statements)
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“…This positive impact of the pressure on the crystallization was expected, as in supercritical CO 2 , the solubility of organometallic compounds increases with the increasing pressure. 38 In addition to the fast diffusivity promoted by the supercritical media, the solubility enhancement is likely to promote the reaction rate of crystal oxide formation.…”
Section: Resultsmentioning
confidence: 99%
“…This positive impact of the pressure on the crystallization was expected, as in supercritical CO 2 , the solubility of organometallic compounds increases with the increasing pressure. 38 In addition to the fast diffusivity promoted by the supercritical media, the solubility enhancement is likely to promote the reaction rate of crystal oxide formation.…”
Section: Resultsmentioning
confidence: 99%
“…Supercritical CO 2 (scCO 2 ) has seen widespread usage as a solvent in numerous industrial processes, notably in foaming, creating porous materials, , extraction, , and manufacturing electronic devices. , This is largely due to its appealing properties, including moderate critical coordinates (with a critical temperature of T c = 304.12 K), reduced viscosity, and enhanced ability to permeate microstructures. The use of supercritical CO 2 for regenerating adsorbents leverages these qualities; its notable diffusivity aids in infiltrating the adsorbent’s pores, while its lower critical temperature and minimal interfacial tension help in preserving the pore framework of activated carbon. As a result, employing supercritical CO 2 for regenerating activated carbon presents a practical alternative to the conventional thermal method.…”
Section: Introductionmentioning
confidence: 99%