Modern dielectrics used in power capacitors can exhibit a dissipation factor lower than 0.005 %, which approaches the limits of presently available measurement techniques. This article reviews techniques, apparatus, and available calibration services for dissipation factor with regard to lowest achievable uncertainties. It is shown that further metrological advances are necessary to lower uncertainty in the measurement to levels at least five times less than presently achievable, in order to ensure traceable and quality-assured measurement of modern dielectrics with such low dissipation factors.