2005
DOI: 10.1103/physrevlett.95.163003
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Precise Calculation of Transition Frequencies of Hydrogen and Deuterium Based on a Least-Squares Analysis

Abstract: We combine a limited number of accurately measured transition frequencies in hydrogen and deuterium, recent quantum electrodynamics (QED) calculations, and, as an essential additional ingredient, a generalized least-squares analysis, to obtain precise and optimal predictions for hydrogen and deuterium transition frequencies. Some of the predicted transition frequencies have relative uncertainties more than an order of magnitude smaller than that of the g factor of the electron, which was previously the most ac… Show more

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Cited by 45 publications
(54 citation statements)
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“…The independent methods for determining α that come closet to our accuracy are the "atom-recoil" measurements, so called because their uncertainty is limited by measurements of recoil velocities in Rb and Cs atoms. They rely on many experiments, including the measured Rydberg constant [58,59], the Rb or Cs mass in amu [60], and the electron mass in amu [61,62]. The needed h/M[Rb] comes from a measurement of the recoil of a Rb atom in an optical lattice [26,28,63].…”
Section: B Most Accurate Determination Of αmentioning
confidence: 99%
“…The independent methods for determining α that come closet to our accuracy are the "atom-recoil" measurements, so called because their uncertainty is limited by measurements of recoil velocities in Rb and Cs atoms. They rely on many experiments, including the measured Rydberg constant [58,59], the Rb or Cs mass in amu [60], and the electron mass in amu [61,62]. The needed h/M[Rb] comes from a measurement of the recoil of a Rb atom in an optical lattice [26,28,63].…”
Section: B Most Accurate Determination Of αmentioning
confidence: 99%
“…The uncertainty of 0.66 kHz is due to the mass ratios given in Eqs. (13) and (14); the uncertainty induced by the fine-structure constant is negligible because we are expressing all quantities in terms of the Rydberg constant. Set (ii).…”
Section: Evaluation Of the Correctionsmentioning
confidence: 99%
“…[13], this value of the deuteron charge radius is mostly based on a theoretical analysis of the most accurately measured transition frequencies in hydrogen and deuterium. An analysis of the world scattering data for the proton leads to a value of r p = 0.895(18) fm (Refs.…”
Section: Introductionmentioning
confidence: 99%
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“…Since their complexity rapidly increases with the loop-order, the calculation of just a single diagram becomes more and more challenging. Steady progress over decades has made weak-field QED the best tested scientific theory, with impressive confirmation by experiment in the case of atomic hydrogen [34], but for strong-field QED both theory and experiment remain still away from that certitude by many orders of magnitude. A calculation of an individual Feynman graph is usually carried out by series expansion with Zα as one of the expansion parameters (with α≈1/137 the fine-structure constant).…”
Section: Introductionmentioning
confidence: 99%