Pre-organized oligofunctional ligands based on <i>rctt</i>-C-naphthyl-resorcinarene: Synthesis and complex formation

Glushko, V. V.; Serkova, O. S.; Smoyan, Gavaz N.; Vasyanina, L. K.; Maslennikova, V. I.

doi:10.1080/10426507.2017.1322591

Cited by 4 publications

(1 citation statement)

References 24 publications

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“…By following the above-mentioned definition, a particular coordination mode can be anticipated (Najafi et al, 2016). This improves the ability of the ligand to complex a given metal due to the chelate effect and other entropic considerations (Glushko et al, 2017). According to the Hancock definition, for an efficient preorganized ligand, the configurational and conformational flexibilities need to be reduced (Carolan et al, 2013).…”

Section: Introductionmentioning

confidence: 99%

Surface-grafted lanthanoid complexes of the tungstosilicate polyanion [SiW₁₂O₄₀]⁴⁻: a synthetic, structural and computational investigation

et al. 2018

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As an extension of our continued interest in the preparation of inorganic–organic hybrids, we report the successful hydrothermal synthesis of sodium tris[triaqua(μ‐1,10‐phenanthroline‐2,9‐dicarboxylato)dysprosium(III)] silicododecatungstate dodecahydrate, {[DyNa(C14H6N2O4)3(H2O)9(SiW12O40)]·12H2O}n or Na[Dy(PDA)(H2O)3]3[SiW12O40]·12H2O (1), and sodium aqua tris[tetraaqua(μ‐4‐hydroxypyridine‐2,6‐dicarboxylato)praseodymium(III)] silicododecatungstate dodecahydrate, {[NaPr(C7H3NO5)3(H2O)13(SiW12O40)]·12H2O}n or Na(H2O)[Pr(pydc‐OH)(H2O)4]3[SiW12O40]·12H2O (2) (in which H2PDA is 1,10‐phenanthroline‐2,9‐dicarboxylic acid and H2pydc‐OH is 4‐hydroxypyridine‐2,6‐dicarboxylic acid or chelidamic acid). Both compounds have been characterized using elemental analysis, IR spectroscopy and X‐ray diffraction methods. Structural characterization by single‐crystal X‐ray diffraction reveals that these compounds consist of [SiW12O40]4− Keggin‐type polyoxometalates (POMs), where a single {W3O13} triad is decorated with a trinuclear Ln complex. Moreover, the decorated polyanions are involved in a series of intermolecular interactions, such as hydrogen bonds and anion–π interactions, resulting in three‐dimensional supramolecular architectures. Density functional theory (DFT) studies were conducted to support these intermolecular interactions in both 1 and 2, and have been rationalized using molecular electrostatic potential (MEP) surface calculations.

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Section: Introductionmentioning

confidence: 99%

Surface-grafted lanthanoid complexes of the tungstosilicate polyanion [SiW₁₂O₄₀]⁴⁻: a synthetic, structural and computational investigation

et al. 2018

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New calix[4]resorcinol rccc diastereoisomer with terminal triple bonds: Synthesis, structural features and reactions

Knyazeva

Syakaev

Habicher

et al. 2023

Mendeleev Communications

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Microwave assisted alkylation of ortho-methyl-tetra-C-naphthyl-resorcinarene and its phosphorylated derivatives with haloalkanes and ethyl bromoacetate

Serkova

Glushko

Егорова

et al. 2018

Tetrahedron Letters

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Pre-organized oligofunctional ligands based on rctt-C-naphthyl-resorcinarene: Synthesis and complex formation

Cited by 4 publications

References 24 publications

Surface-grafted lanthanoid complexes of the tungstosilicate polyanion [SiW₁₂O₄₀]⁴⁻: a synthetic, structural and computational investigation

Surface-grafted lanthanoid complexes of the tungstosilicate polyanion [SiW₁₂O₄₀]⁴⁻: a synthetic, structural and computational investigation

New calix[4]resorcinol rccc diastereoisomer with terminal triple bonds: Synthesis, structural features and reactions

Microwave assisted alkylation of ortho-methyl-tetra-C-naphthyl-resorcinarene and its phosphorylated derivatives with haloalkanes and ethyl bromoacetate

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Pre-organized oligofunctional ligands based on rctt-C-naphthyl-resorcinarene: Synthesis and complex formation

Cited by 4 publications

References 24 publications

Surface-grafted lanthanoid complexes of the tungstosilicate polyanion [SiW12O40]4−: a synthetic, structural and computational investigation

Surface-grafted lanthanoid complexes of the tungstosilicate polyanion [SiW12O40]4−: a synthetic, structural and computational investigation

New calix[4]resorcinol rccc diastereoisomer with terminal triple bonds: Synthesis, structural features and reactions

Microwave assisted alkylation of ortho-methyl-tetra-C-naphthyl-resorcinarene and its phosphorylated derivatives with haloalkanes and ethyl bromoacetate

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Product

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Surface-grafted lanthanoid complexes of the tungstosilicate polyanion [SiW₁₂O₄₀]⁴⁻: a synthetic, structural and computational investigation

Surface-grafted lanthanoid complexes of the tungstosilicate polyanion [SiW₁₂O₄₀]⁴⁻: a synthetic, structural and computational investigation