“…It was also suggested that A-site ionic size mismatch may cause a glass-like disorder state, leading to a highly magnetic inhomogeneity. 62 Recently, Ulyanov and co-workers 64 have used the electron-spin-resonance spectroscopy for studying praseodymium manganites and found FM and anti-FM interactions associated with both ion types (Pr 3+ and Mn 3+,4+ ) persist in it throughout the temperature range, even above critical temperature. For both wide- and narrow-bandwidth manganites, several investigations of resonant signals (related to the decrease of resonant intensity, the broadening of linewidth, and temperature dependences of the resonant field) in the paramagnetic region show the presence of FM clusters, spin–phonon and/or spin–orbit interactions.…”