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Clean and Efficient Transformation of CO2 to Isocyanic Acid: The Important Role of Triatomic Cation ScNH+

“…The cyanate ion, NCO – , is a quite stable functional group, and salts containing this ambidentate ligand are commonly found in organic chemistry. The isocyanates are potentially useful as carbamoyl synthons for organic synthesis. , In addition, the NCO unit is also an important building block in the field of pseudohalogen chemistry. , Moreover, the conjugate acid of NCO – , isocyanic acid (HNCO), is the simplest compound, possessing four main biogenic elements, and it was one of the first polyatomic molecules observed in the interstellar gas. It is highly desirable to develop a simple HNCO-producing reaction with high selectivity and reactivity by using CO 2 as the source and to understand the reaction mechanism.…”

Chemical ionization mass spectral analysis of pinacolyl alcohol and development of derivatization method using p-tolyl isocyanate

“…E-mail: mrvsmurty@iict.res.in; vairamani@iict.res.in; Fax: +91-40-27193156; Tel: +91-40-27193482 R-NCO + R 1 -OH / RNHCO-OR 1 Several isocyanates namely phenyl isocyanate, hexamethylene-1,6-diisocyanate (HDI), 4,4 0 -methylene bis (phenyl isocyanate) (MDI) etc., and their substitutes are estimated as their amine or alcohol derivatives. [11][12][13][14][15][16][17] The EI mass spectrum of trimethylsilyl (TMS) derivative of PA is available in the commercial mass spectral library, 18 and derivatization of PA with BSTFA (N,O-bis (trimethylsilyl) trifluoro acetamide) is mentioned. 19 But to the best of our knowledge, no experimental details are available in literature on the silylation of PA with BSTFA.…”