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Golovleva, V. K.; Dunaevskii, G. E.; Levdikova, T. L.; Sarkisov, Yu. S.; Tsyganok, Yu. I.

doi:10.1023/a:1011303713689

Cited by 13 publications

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“…This green technology is clean and has zero energy consumption. Pure water, as a polar and associative liquid, can modify its intermolecular bonds in an applied magnetic field, changing to a metastable state but keeping that state for some time . Based on Mosin and Ignatov's theory, the applied magnetic field directly affects the structure of water because of the polarization of water molecules.…”

Section: Introductionmentioning

confidence: 99%

Ligand‐free, copper‐catalyzed, one‐pot, three‐component synthesis of novel 1,2,3‐triazole‐linked indoles in magnetized water

Bakherad

Keivanloo

Bakherad

et al. 2019

J Chinese Chemical Soc

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Magnetized water (MW) is used as a green and new solvent-promoting medium for the one-pot, three-component synthesis of novel 1,2,3-triazole-linked indoles catalyzed by copper iodide. A broad range of 2-aryl-1-(prop-2-ynyl)-1H-indole-3-carbaldehydes were reacted with alkyl halides and sodium azide via coppercatalyzed azide-alkyne cycloaddition reactions in MW in the absence of any ligand. This method offers the advantages of short reaction times, green procedure, low cost, simple work-up, quantitative reaction yields, and no need for any organic solvent.

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Section: Introductionmentioning

confidence: 99%

Ligand‐free, copper‐catalyzed, one‐pot, three‐component synthesis of novel 1,2,3‐triazole‐linked indoles in magnetized water

Bakherad

Keivanloo

Bakherad

et al. 2019

J Chinese Chemical Soc

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The effect of magnetized water on the oxidation reaction of phenol derivatives and aromatic amines by horseradish peroxidase enzyme

Emamdadi

Gholizadeh

Housaindokht

2020

Biotechnology Progress

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The present study aimed to investigate, for the first time, the rate of the oxidation reaction of some derivatives of phenol and aromatic amines, that is, pyrogallol, catechol, resorcinol, ortho-aminophenol, meta-aminophenol, para-aminophenol, orthophenylenediamine, and para-phenylenediamine, in the presence of hydrogen peroxide in pure and magnetized solvents using horseradish peroxidase enzyme. The reaction was studied in the absence and presence of a magnetized solvent under completely identical conditions. The results showed that magnetized solvent could change the structure of the enzyme and reduce its activity. In addition, it affected the rate of oxidation of the selected derivatives through altering the strength of the hydrogen bonds of the system. The changes in the structure and activity of the enzyme were examined using UV-Vis and fluorescence spectroscopy as well as viscosity measurement technique. Examination of the secondary structure via the far UV-CD spectrum indicated the increase in the alpha helical structure in the magnetized solvent. When dissolved in a magnetized solvent, hydrogen peroxide as an enzyme substrate reduced the rate of enzymatic reaction and provided lower saturation conditions for the enzyme compared with when it was dissolved in the pure solvent.

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Catalyst-free green synthesis of tetrahydro-benzo[b]pyrans in magnetized water: experimental aspects and molecular dynamics simulation

et al. 2019

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Cited by 13 publications

References 0 publications

Ligand‐free, copper‐catalyzed, one‐pot, three‐component synthesis of novel 1,2,3‐triazole‐linked indoles in magnetized water

Ligand‐free, copper‐catalyzed, one‐pot, three‐component synthesis of novel 1,2,3‐triazole‐linked indoles in magnetized water

The effect of magnetized water on the oxidation reaction of phenol derivatives and aromatic amines by horseradish peroxidase enzyme

Catalyst-free green synthesis of tetrahydro-benzo[b]pyrans in magnetized water: experimental aspects and molecular dynamics simulation

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