2009
DOI: 10.1134/s1023193509080163
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Potassium-conducting solid electrolytes in the systems K2 − 2x Al2 − x M x O4 (M = Nb, Ta)

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Cited by 4 publications
(7 citation statements)
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“…A computational study on the Na þ conductivity of Na 3 PS 4 also predicted the positive effect of enhanced charge carrier density in non-layered structures by substantially improving ionic conductivity. [23] K 2þx Mg 1Àx/2 SiO 4 ionic conductivity values in this study are among the highest reported in the literature compared to several similar polycrystal K-ISICs, especially at low temperatures [7,10,13,[17][18][19][20][21][24][25][26][27][28][29][30][31][32] (Figure 1b, Table S4, Supporting Information). These conductivity levels were achieved using a chemical compound without non-abundant elements, such as Sb or Te, or metals with multiple ionization states, such as Fe.…”
Section: Electrochemical Characterization Of the Electrolytesupporting
confidence: 47%
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“…A computational study on the Na þ conductivity of Na 3 PS 4 also predicted the positive effect of enhanced charge carrier density in non-layered structures by substantially improving ionic conductivity. [23] K 2þx Mg 1Àx/2 SiO 4 ionic conductivity values in this study are among the highest reported in the literature compared to several similar polycrystal K-ISICs, especially at low temperatures [7,10,13,[17][18][19][20][21][24][25][26][27][28][29][30][31][32] (Figure 1b, Table S4, Supporting Information). These conductivity levels were achieved using a chemical compound without non-abundant elements, such as Sb or Te, or metals with multiple ionization states, such as Fe.…”
Section: Electrochemical Characterization Of the Electrolytesupporting
confidence: 47%
“…K 2+ x Mg 1− x /2 SiO 4 ionic conductivity values in this study are among the highest reported in the literature compared to several similar polycrystal K‐ISICs, especially at low temperatures [ 7,10,13,17–21,24–32 ] (Figure 1b, Table S4, Supporting Information). These conductivity levels were achieved using a chemical compound without non‐abundant elements, such as Sb or Te, or metals with multiple ionization states, such as Fe.…”
Section: Resultsmentioning
confidence: 49%
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“…439 Despite the existence of polymer electrolytes exhibiting high K + conductivity, the literature on solid-state potassium-ion conductors remains relatively scarce. 443–476 As a result, the current focus of research revolves around enhancing the ionic conductivity of solid-state potassium-ion conductors. However, it is essential to note that other pivotal electrochemical properties often remain insufficiently characterised, including electrochemical stability, ion selectivity, mechanical properties, and assembly techniques.…”
Section: High-energy-density Potassium-ion Battery Full Cell Designmentioning
confidence: 99%
“…The specific electrical conductivity of the samples at 800 K and the activation energy values of the antimony tungstate containing Me x K 1-x SbWO 6 (Me = Na, Li) with the same amount of sodium and lithium ions (x = 0.4). The value of the ion radius (given from [15][16][17][18][19][20][21][22][23][24]) and the activation energy calculated from the data on the temperature dependence of the electrical conductivity are shown in Fig. 1.…”
Section: Tablementioning
confidence: 99%